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| VEHICULOS DE MOTOR ELECTRICO | CONTAMINACION | CIRCUITO | AIRE | AGUA | DOCTORADO EN MEDICINA AMBIENTAL |
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| VEHICULOS DE MOTOR ELECTRICO | CONTAMINACION | CIRCUITO | AIRE | AGUA | DOCTORADO EN MEDICINA AMBIENTAL |
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Synthetic Forest is the Portal to the Conjunctive Exploration of Matter: Roots to Electronics, from the Fundaments of Alchemy to Biotechnological Applications, from Gluconeogenesis to Photosynthesis. This Forest spurs a Center of Technological Development over the Balanced use of Natural Resources.
2021 TOKYO OLYMPICS
Inside the Synthetic Forest you will be able to Explore your Interests in Our Global Directive of Eco-Technological Development.
The Synthetic Forest is the Contraposition of what Nature Made and Makes and what Culturally Derived Practices of Technology Derived and Will Derive for the Future, so in this way Every Effort of Remediation of the Planet is included in the Prospective View of what the Synthetic Forest is and will be. The Continuous Evaluation of Our Use of Technology along the Eco-Temporal Evaluation of Use and Resources is what prompts Us Here.
THE BLACK HOLE
Every Circuit contains a source of electrons (or voltage) and returns electrons either to a storage or to ground.
Every Mass Balance is of the form Input + Generation - Consumption = Output.
Every Energy Balance is alike, even when the Laws of Physics are bent.
Every Economic Model must possess a Black Hole to return the system to a state where every calculation holds true.
If you print money every day and enter into any economical model without retiring money on the other side you will inevitably create inflation.
Because currencies are virtual, because anything precious is relative to the observer, every economical model must posses a Force of Return to balance the equation.
In a virtual economy something must be consumed for any piecewise monetary value to be substantiated, otherwise a virtual falsehood is created. Illusions cannot be economical instruments by default, or more explained, because any virtual economic system that possesses the ability to generate piecewise monetary value, paper, stocks, market inflation, is potentially resulting in enslaving populations on a treadmill that has no end, it is literally like finding the edge of the universe, the more society looks to settle debt the inevitability of generation of poverty results because there are individuals that will be inevitably sentenced to poverty, so the eradication of poverty becomes illusional in reality. This contradiction can only be corrected if the economic system opens a Black Hole to correct any expansive forces in the market. This idea does not counter any economic system. This idea should be a fundamental understanding of every economist, and cannot be countered with pessimism. The role of regulatory agencies then becomes the settling of debt or in metaphorical context Opening The Black Hole. Debt collection is extremely important because it is the contractile force of the Economy, but without a real governmental action to collect debt actively by settling it, goverment is demonized because it fails to collect debt without the ability to settle poverty. Because overconsumption of every kind of resource, organic, inorganic, is tied to pollution generation governments should actively concert Moratoriums and Debt consolidation as victories for its people. However complex the algorithm, the compiler must understand the language for the program to run. What we are trying to say with this is that the rules must return true for the system to be True in reality. No mathematician is satisfied watching countries drown in debt and impossibilities. This is why International relations are extremely important. And why it is time for the International Community to decree a Moratorium over a large portion of consumable goods. Tarifs drive inflation, every body knows that. What is needed is a Moratorium of consumable goods, a reduction in global working hours and an international pact to settle debts without recreations of false virtual markets. The Pandemic arose sufficient data that NASA can without a doubt state that the Planet's ecosystem is highly recuperable to prevent a runnaway reaction. Today we are at 416.25ppm of CO2, a number that should not be equated to 100Million displaced inhabitants for rising waters, exploitation of workers, generation of waste etc. Moratoriums can be achieved by introducing benefits to workers, but large Moratoriums need to be decreed. If the entire globe stops manufacturing and consuming for one month each year, the planet could revert its warming trend, perhaps more than a month is needed, but it would be a global victory for every country. The realization that we need less not more of everything to live could bring the planet into a New Era of Absolute Peace and prosperity for every country.
Department of Energy
There are Further Actions to This Virtual Proposal. Only adherence to a Form of Understanding that Humans are the Drivers of the Economy is that We can Remediate what is lacking in the Human Experience: Greater and Broader Quality of Life.
The Synthetic Forest also Prompts towards PROJECT MORATORIUM: a Reduction in Total Global Working Hours: There is Zero reason why someone in Asia has to work 3 times as much as a Person in a First Economy Country,
and this Reason in Corrolary to the Moral Argument that if One Excess Persists then the Responsibility to uphold Human values, i.e. Consciousness, Dictates.
So if there is a Moral Responsibility to Care for Nations far away... The Planet is One, so the Imperative is Obvious, We Must Care.
How we Care is the Big Question, and before Water Quality becomes a Driver of Conversations demanding International Pressure to Countries far away to reduce their Culturally Accepted Practices,
We must have the Conversation and enact Laws that set the Example.
That is why I created the Wind Bar: The Wind Bar is the Center for the Exchange of Culturally Accepted Ideas and how the Ideas can be contraposed "In-Play" to ferment Dialogue that leads to Practical Solutions.
The World will not be saved in One Day but Love for the World can save It. The Change of Attitudes takes an Infinitesimal Moment and that is how, with Conscious Efforts of implementing Pragmatic Solutions, We can generate a More Perfect Unity of Nations.
The GREEN NEW DEAL is a Solution, a Plan to remodel the Energy Grid of the United States through investment in civil infrastructure that spans both Microgrid projects and Large Scale Green Energy projects that may span
Photovoltaic Systems Array, Wind Turbine Farms, and Fusion Reactors. -in progress.
The budget available for investing in technological feats to reach a stage of Infinite Energy, Optimum Work Generation and Free Healthcare,
results only from the ability of the government to drive investment through the establishmet of public policy, taxation rules and by printing money.
It is the government's role to establish the rules by which Debt becomes an obligation per se (rules and contracts), and secondary an obligation to repay an equitable and agreed upon measure of value (establishing a fair market).
If the government opted for policies to for example eliminate Student Debt, then by the allocation of monies to eliminate student debt the measure of how much resources are equated to capital is defaulted.
These are the fundamental abstract concepts that create the economy. The argument in pro of the Green New Deal is that the government can generate an economy based on ameliorating the Nation's capacity to produce clean energy by shifting the priorities of where government spends its money. [Beyond equitable exchanges of goods, services and monetary value, it must be understood that there is a real physical concept of Debt that exists in the form of Depletion, Depletion of Materials that cannot be replenished, Depletion of Time that cannot be recuperated, and Depletion of Human Resources whose efforts are lost in actions through time. This is a fundamental argument about what debt really is which is extremely important to be understood because in the economy there isn't any rule about conforming to the forms of depletion that result in the economy. -in progress.
Every resource has a limited distribution in Nature.
Their prices are determined by the market forces but if one resource was needed by a sector of society that couldn't receive it the rules of the market can be changed to result in more equitable distribution of the resource. -in prograss.
Prices are determined by the interactions of the market and how the market is regulated by the government.
Stated otherwise, Debt is the total sum of Depletion of Resources, whether the resource is a human reource or a material resource.
We should confront problematics with the realization that the government is the Printer of Currency and the Referee of the Economy, the entity that sets the boundaries and rules on which corporations play.
The GREEN NEW DEAL is Paramount on the Completion of the Improvement Along and Against Climate Change. Climate Change is Global Warming : a Runaway Reaction from which Humans may not survive. 130°F in New York City Summer would be fathomable at this Present Rate Catastrophic beyond recognition. The Measures to complete the Green New Deal require Tough Directed Enforcement and today the World is Ready, Anxious, to Establish the Measures that reduce Total Waste Generation.
POVERTY is UNACCEPTABLE
LACK of HEALTH is UNACCEPTABLE
LACK of WORK is UNACCEPTABLE
The drivers of The Green New Deal are Elemental.
In the Philosophy of Manufacturing there are No Losses: i.e. Goods Made and Goods Sold occur in One Spot: the Client is at the Doorstep of the Manufacturing Arena LITERALLY, so there are no Eco-Temporal losses of Manufacturing Philosophically but Realistically there are Losses of Time-Money-and Product Losses by Competition.
Understanding that COLLUSION CANNOT BE TAUGHT brings an Understanding to Global Current Economic Drivers and INDICATORS remain. The only counter to Private Industry Collusion is the enforcement of Fair Market Policies by the Government. There must be arbitration in every level of society because as it has been shown certain drivers in the private sector believe that profiteering is the absolute end of Capitalism. The Continuity of the Answers Remains on How the Questions are Continually Reevaluated to Perfection, so the Generation of Concepts does not cease Until Perfected Systems Exist to Meet the Demands of Problem Generators and Problem Solvers. THE DRIVERS OF EVOLUTION WERE ALWAYS ENVIRONMENTALWIND BAR
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STATE OF THE COLONY: INSTITUTIONALIZED COLONIALISM V. FISCAL ADMINISTRATION
STATE OF THE COLONY: INSTITUTIONALIZED COLONIALISM V. FISCAL ADMINISTRATION
STATE OF THE COLONY: INSTITUTIONALIZED COLONIALISM V. FISCAL ADMINISTRATION
STATE OF THE COLONY: INSTITUTIONALIZED COLONIALISM V. FISCAL ADMINISTRATION
STATE OF THE COLONY: INSTITUTIONALIZED COLONIALISM V. FISCAL ADMINISTRATION
LEY 17 POLITICA PUBLICA ENERGETICA (Sustituye LEY 83)
LEY 114 TRANSFORMACION
LEY 57 TRANSORMACION Y ALIVIO
LEY 120
LEY 211 POLITICA PUBLICA
DatosLas ayudas Federales en Administracion fueron necesarias hace mucho tiempo pero resulta imposible correlacionar una imposicion legal con poder decisional sobre la Isla y que sus ciudadanos no tengan una voz y voto en los mismos.
STATE OF THE COLONY
APPOINTMENTS CLAUSE v. TERRITORY CLAUSE
"The specific governs the general"
SEPARATION OF POWERS
1947 Government
1952 Constitution
(option)Historical interpretations of the Appointment's clause would default to colonialism rule because Article IV supercedes any Puerto Rican resolve to acquire greater level of representation in Congress. (Ref. 1900 Foraker Act, Jones Act).WIND BAR
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DISCUSSIONS ABOUT THE LOTUS SUTRA
Information Transport in Historical Literature.
Collective works referencing Law, Science, Herbs, and Medicine.
DISCUSSIONS ABOUT THE LOTUS SUTRA
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Get Quotations, Get Pricing, Get Information for your Engineering, Scientific or Personal Interest Applications. BUSINESS PLAN: Our Business Plan is to make Synthetic Forest a Social Networking Platform.
ECONOMIC STREAMS: STREAMS OF INCOME: Dear Investor, Synthetic Forest is solely owned and operated by Yerai Oliveras. Synthetic Forest seeks sponsorship at negotiable rates of return for Series A Funding.
At this state what we seek is Turnover Capital to Integrate software programming into a more marketable product appealing to EVERY Product Sector in between Herbally Derived Product to Syntheticaly Derived Chemicals. Our breadth of Clientele is Ample and that can be targetted with the Trademarked name of Synthetic Forest.Secondly, We seek Sponsorship to filter out competitors. For example, we would only cater to Nike, New Balance and Exclude Adidas or sell only Adidas and Exclude New Balance and Nike, and this model can be applicable to Biotechnologeical Companies seeking the POPULARIZATION of trending technology. Are you onboard Shimadzu, Agilent, Gentech, etc.
The Drivers for Biotechnological R&D are High Tech companies that are not well known and I having a background in Chemical Engineering, Chemistry, Manufacturing, Pharmacology, Genetics, Analytical and Organic Processes can serve as a driver to produce both articles, and the Center for Information where such products are talked about, networked, trobleshooted in FORUMS and Progressed upon.
REVENUE STREAMS in the form of Publications, Announcements, Trends in Technology, Popularization of High End Products and Technology and also weeding out the vast trends of misinformation that abound in the Internet.
REVENUE STREAMS in the form of Services by consulting of professinals directly involved in The Synthetic Forest. We can hire and train for a multitude of project types and by providing Engineering Services the site can be funded.
No memberships have been contemplated for the public streams of information but memberships can become revenue streams if the website offers high end software tied to High End Technologic Development and 3-D VIRTUAL REALITY is the forthcoming generation in Eco-Technological Development for which We at Synthetic Forest seek to be at the forefront.
REVENUE STREAMS: Distribution: Discounts: Synthetic Forest does not seek to become a direct distributor of any products, there are already heavy competitors of product distributors. What we seek is to centralize the discussions about those products and to display them in a Virtual Center. For this we have elaborated a plan for establishing a discount center for technologies that are distributed elsewhere. For example: a visitor to the site opens a user account and navigates through the eShop and wants to buy a solar panel, then the visitor accesses a digital discount from Synthetic Forest that can be used to buy directly from Solar Panel Distributor. In this way our Center can allow for product-on-display competition and for discount competition, establishing two levels in addition of what is discussed in the Forums.
CURRICULI: EDUCATIONAL DRIVERS IN THE ECONOMY
Human Resources are the Brains driving the Economy, not Artificial Intelligence. Because Humans will FOREVER dictate what Machines Make and Follow the Orientation of Humans towards maximizing productivity is Key to Urban Development. Of this Proficiency in the Sciences is key albeit where science is practiced, be it in music, marketing, cancer research or managing a small store, proficiency in the sciences will be the driver of education towards a more sustainable future and MUST be supported through efforts of popularization, socialization, and networking using the Internet. It is our goal to be able to standardize Curriculums globally to drive economic development in balance with resources i.e. there is no excuse to develop 100 engineers to unemployment. A reality check should abound that on scarcity, the methods and educational tools taught should be transparently limited and new methods developed to keep social productivity, on the other hand if social development results in a competition to major losses, or if social mechanisms aren't equating talent then these methods must be continually evaluated. That's why we're here.
CURRICULI: EDUCATIONAL DRIVERS IN THE ECONOMY
MARS TERRAFORMING
Were're also here because We want to develop the Next Generation of Astronauts that will settle on THE NEXT PLANET: MARS.
Our goal of Centralizing Education is alongside the efforts to live on Mars. What are the latest trends in technology development here on Earth that are applicable to Terraforming Mars?
There's water on Mars, so what's next?
MARS TERRAFORMING END
Branches
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Elements Bar
Mars Terraforming
yerai@syntheticforest.com
NUTRITION TRENDS: NUTRITION TRENDS: NUTRITION TRENDS
NUTRITION TRENDS: NUTRITION TRENDS: NUTRITION TRENDS
NUTRITION TRENDS: NUTRITION TRENDS: NUTRITION TRENDS
NUTRITION TRENDS: NUTRITION TRENDS: NUTRITION TRENDS
What to Eat, What not to Eat.
When to Eat and When not to Eat.
Best references and best Nutritional Consultants Here.
For all your needs inside the SSFF.
What is Healthy?
Lasers in Medicine
Inside The Synthetic Forest 2020 you will find the best Nutrients for all your exercise needs.
SSSFFF is guided by scientific and empirical methods that will drive your performance needs to new heights.
The Body is a Machine. The Mind is a Synthetic Forest. Your body is a Chemical Site.
Next time you stop to put gas in your vehicle make sure you've counted Essential Ions, not only Essential Amino Acids.
Get Ready: You are about to encounter a New Source of Energy here...
Lets start off Creating a couple of Chararacters to develop Dietary Programs
1- Works 50 hours a week. Has 2 children. Wakes up at 6:00am. Goes to sleep at 12:00pm. Drinks socially but does not smoke.
2- Works 50 hours a week. Has no children. is Asthmatic.
3- Works 40 hours a week drinks, does not smoke.
4- Works 40 hours a week drinks, and smokes. No preexisting condition.
5- High school athlete. Practices sports 3 to 5 days a week.
6- Professional Athlete seeking strength over endurance.
7- Professional Athlete seeking endurance over strength.
8- Bodybuilder non-competitive.
9- Bodybuilder competitive.
10-Student.
FIRST NOTEDietary Requirements for 1 through 10
Nutrient | Type | Origin | Recommended Dose | Source | Benefits |
Vitamin A | Vitamin | Group of Organic Compounds | Carotenoids Retinyl Palmitate to Retinol |
Growth, Development, Eye Functions | |
Vitamin B | Vitamin | Group of Organic Compounds | Thiamine Niacin Riboflavin |
Cell Metabolism | |
Vitamin C | Vitamin | L-Ascorbate | 100mg - 300mg | Ascorbic Acid, Tomato, Chili Peppers, Bell Peppers, Green Peppers. | Enzyme Co Factor Prevents Scurvy Antioxidant Food Additive |
Vitamin D | Vitamin | Fat Soluble Steroids | UV + 7-dehydrocholesterol | Calcium Balance Metabolism Prevents Rickets: Osteomalacia |
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Vitamin E | Vitamin | Fat Soluble | 7-20 mg/day | Ample Wheats, Oils, Fruits |
MANY Gene Expression Skin Tone Antioxidant Coagulation |
Vitamin K | Vitamin | Fat Soluble Organic Compounds of variable Isoprenoid Chain Length | Kale, Spinach, Mustard | Coagulation Primarily Calcium Binding |
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Folic Acid | Vitamin | Vitamin B | 400 mcg (.5-20mcg stored) |
Folate | DNA repair and Methylation Co Factor |
Salts | Salt | Salts are Ionic Bonds | Salts | Stimulation of Neuronal Activity CoFactors Protein Stability |
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Carbohydrates | Sugars | Sugars | |||
Fats | Fats | Fats | |||
Co Factors | Co Factors | Co Factors | |||
Water | See below | See below | Structure Metabolism Hydration |
Potassium | Potassium Iodide | ||||
Iron | Ferric Orthophosphate | ||||
Sodium | |||||
Phosphorus | |||||
Zinc | Zinc Sulfate | ||||
Manganese | |||||
Chloride | Choline Chloride | ||||
Calcium | |||||
Magnesium | |||||
Copper | |||||
Molybdenum | |||||
Selenium | Sodium Selenate | ||||
Chromium | |||||
Pantothenic Acid |
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Riboflavin | |||||
Biotin | |||||
Niacin | Niacinamide | ||||
Cyanocobalamin | |||||
Thiamine | |||||
Folate | |||||
Oils | Palmitate | ||||
Cholesterol | |||||
Sulfates | Cupric Sulfate Manganese Sulfate |
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Carbonates | Calcium Carbonate | ||||
Fiber | |||||
Sugars | Sucralose | ||||
Acids | Ascorbic Acid | ||||
Citrate |
SECOND NOTE Types of Workout Routines for 1 - 10
Base Level | Ramp Up Level | Rest Level / wk | Goal | |
1 | Isolation vs Total Body Workout | Weekly Ramp Up cycle after 4 weeks. | 2-3 days | 8 hours of sustained 2x heart rate = Calorie Consumption to match calorie intake. |
2 | Isolation vs Total Body Workout | 2 days | Increase Oxygenation Efficiency. Improve Lung Capacity. | |
3 | Osteoporosis, Tissue Breakdown Prevention | Daily Ramp up to max | 2 days | Prevent Muscle and Bone Clastification Stimulate hormonal synthesis |
4 | Increase CardioPulmonary Level. Increase Muscle Mass. | 4 | Maintain Balanced Caloric Input/Output | |
5 | Muscle Growth and Muscle Development | Mass increase yield by increasing Reps. | 2-3 days per week. | Match Slow to Fast Muscle Response to Sport. |
6 | Deep Muscle strength | Anabolic Growth | 2 days per week | Power = FXD Efficiency = Wout/Win |
7 | Develop Muscle Memory, Sustained Cellular response at optimum level. | Anabolic / Catabolic Balance Trials at optimum level to chart dietary requirements. |
1 day per week or less | Power = FXD Speed = dd/dt Sustained 80% yield over time increase. |
8 | Sustain CardioPulmonary Level. Prevent Muscle Breakdown | 1.5 | Increased Muscle Mass and Tone | |
9 | Sustain CardioPulmonary Level. Prevent Muscle Breakdown | 1.5 | ||
10 | Sustain CardioPulmonary Level. Prevent Muscle Breakdown. | No Overwork | 3-4 days per week | Improved Circulation |
THIRD NOTE HYDRATION
How much water should you ingest? Should you ingest water during Exercise? Should you ingest water prior to exercise?
Water is a small molecule that bonds to itself, making a larger molecule by virtue of interaction. Water interacts with most substances because it is dipolar. Make it H-OH, or write it H-O-H, or write it +/- +H-O-H+ there is an interesting interaction of water with all that lives. Protonation changes the Amino Acids into Acidic or Basic Form. So water loss creates a large interaction in your body with amino acids, evidently during exercise a bit of water helps and an excess of water creates weight. So there is an OPTIMAL amount of water that can be ingested.
Count all food as .60 water. Recall WATER IS FOOD!!! when you drink water After exercise, you digest the breakdown of Storaged Fats and Sugars by the Process of GLUCOLYSIS. We'll Explore GLUCOLYSIS In-Depth in THE SYNTHETIC FOREST< Glucolysis.
Take 2.5 Liters of Water as the Average recommended intake. Is this good? First calculate your body volume...... get ready to mop the floor... fill in your tub with a known amount of water in Liters. Take your time. Mark the low water level. Then get in, completely, you will need a large container if you don't fit completely in the tub. Mark the high mark and get out. This is the volume of water lost and the difference is your body's volume. Divide 2.5 by your body volume. 2.5/X = fraction of water per total body volume... Enter Body Volume Index or BVI.
Essential Amino Acids at SSSFFF | |
Polar unchargedamino acids Hydrophilic (Serine, Threonine, Glutamine, Asparagine, Tyrosine, Cysteine) Form hydrogen bonds |
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Cystein can form covalent disulfide bonds Proline has a unique structure and causes kinks in the protein chain |
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The nonpolar amino acids (Glycine, Alanine, Valine, Leucine, Isoleucine, Methionine, Phenylalanine, Tryptophan, Proline) Hydrophobic and are usually found in the center of the protein. They are also found in proteins which are associated with cell membranes. |
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Electrically Charged Amino Acids. Charged. Aspartic Acid, Glutate, Lysine, Arginine, and Histidine Electrical properties that can change depending on the pH |
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Proline | |
Essential Amino Acids | F H I K L M T V W |
Dispensable | A D E N S |
Conditional | C G P Q Y |
Requirements | Between 10-40 mg/kg |
Amount of water per Amino Acids | ? |
Net Protein Utilization | ? |
Protein Digestability Score | ? |
Feed Conversion | ? |
Available Value | ? |
Metrics for Ingestion | Measure by Performance... Measure by Recuperation... Measure by Tape.... Measure by Ingestion... Measure by Development Over Time... |
FOURTH NOTE OPTIMIZATION and RECOVERY
FIFTH NOTEPERFORMANCE METRICS
SIXTH NOTE Understanding LONG TERM EFFECTS
Are you a professional athlete in your 60's? write to us at info@syntheticforest.net
Synthetic Forest 2020 All copyrights reserved.
FOURTH NOTEOPTIMIZATION and RECOVERY
Meal | Morning 0600 | Mid Morning 1045 | Lunch 1330 | Lunch Snack 1600 |
Dinner 2000 |
Dinner Snack 2300 |
Total Water | Total Calories 1Cal = 4.2Joules 1 food calorie = 1 kCal |
Yield Heat Lost x Mass Gained x Performance Factor |
Cost |
1 | Cereal + Fruit ? Eggs (2) + 3 slices of bacon dried + 2 Wheat Toasts Yogurt |
Bottled Liquid Meal Yogurt |
Coffee | Bottled Liquid Meal | Steaks Salmon Salad |
Bottled Liquid Meal | 2.5L | 2000-3000 3000-4000 |
10.00USD? 30.00USD? |
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2 | Cereal + Fruit ? Eggs (2) + 3 slices of bacon dried + 2 Wheat Toasts |
Bottled Liquid Meal | Tea | Fruit Cereal Yogurt Nothing |
Rice and Beans Steak |
Bottled Liquid Meal | 2000-3000 3000-4000 |
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3 | Cereal + Fruit ? Eggs (2) + 3 slices of bacon dried + 2 Wheat Toasts |
Bottled Liquid Meal | Coffee | Steaks Salmon Salad |
Bottled Liquid Meal | 2.5L | 2000-3000 3000-4000 |
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4 | Yogurt | Toast Yogurt Cereal |
Yogurt Toast Cereal |
2000-3000 3000-4000 |
$200-300/month? 100-200/month? 400-600/month?
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5 | Cereal + Fruit ? | Steaks Salmon Salad |
Yogurt Toast Cereal |
2.5L | 2000-3000 3000-4000 |
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6 | Cereal + Fruit ? | Yogurt Toast Cereal |
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7 | Cereal + Fruit ? | Steaks Salmon Salad |
Yogurt Toast Cereal |
2.5L | ||||||
8 | Cereal + Fruit ? | Yogurt Toast Cereal Protein |
Variable 2-4L |
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9 | Eggs (2) + 3 slices of bacon dried + 2 Wheat Toasts | Salmon + Rice + Spinach | Protein + Carbohydrates + Vegetables | Yogurt Toast Cereal Protein |
Variable 2-4L |
2000-3000 3000-5000 5000+++ |
1000-1500/month
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10 | Skipped? Bottled Liquid Meal |
Skipped? Bottled Liquid Meal |
Binge? Fast Food? Coffee |
Bottled Liquid Meal Nothing |
Fast Food? Coffee |
Bottled Liquid Meal Cereal Coffee Yogurt |
1L 2-4L |
2000-3000 3000-5000 5000+++ |
1000-1500/month |
FOURTH NOTE: WHAT do World Athletes Eat?: Here's what a Bodybuilder eats for ....
Serena Williams Workout
Triathlon: Ironman Triathlon: 1-1.5h Swimming + 120miles in the Bike + 1.5hours at 11minute/mile..............................................................................................................................................................................................................................................?
Are you interested in Training for Sport? write to us at info@syntheticforest.net
So whithout entering the realm of Optimization for Humans.... soon... OPTIMIZATION and RECOVERY...finished?
FOURTH NOTEPERFORMANCE METRICS: Linear Progression vs Exponential Growth: What is the natural progession of improvement: Understand the ... Exponential phase, Linear Development, and Saturation....Maximal.... Just like Saturation Kinetics.... Recall your body is made up of Proteins.
FIFTH NOTE: Understanding the Risks of EXTENUATION, OVEREXERTION, FATIGUE, and PHYSIOLOGICAL EFFECTS
Call your doctor... Rhabdomyolisis... Your body is auto destroying... When to rest and when to over rest...
Push yourself UNDER SUPERVISION.
What is Overwork .... 10 miles, 100 miles, 300 pounds... what are the risks? How many Heart Attacks can you survive?
FATIGUE: First answer the question: Have you
OVEREXERTION: CASE STUDIES
OVEREXERTION: EXERTIONAL RHABDOMYOLYSIS
RUPTURED DISKS
LUMBAR/THORACIC/CERVICAL: PINCHED NERVE, BULGING DISK, HERNIATED DISKS
FAKE MEDICINE
FAKE MEDICINE
FAKE MEDICINE
FAKE MEDICINE
FAKE MEDICINE
FAKE MEDICINE | QUESTIONS TO ASK YOUR ATTORNEY
FAKE MEDICINE | QUESTIONS TO ASK YOUR ATTORNEY
FAKE MEDICINE | QUESTIONS TO ASK YOUR ATTORNEY
FAKE MEDICINE | QUESTIONS TO ASK YOUR ATTORNEY
|Fake Medicine | Questions to ask Your Attorney
What are Irreversible Actions
Arrest | Negligence | Recklessness | [ ] Promissory Estoppel | [ ] Partial Liability
Arrest | Torture | Involuntary Treatment Do You Agree
Arrest | Torture | Involuntary Treatment →→→→→→→→→→ The Person Did not Help Me →→→→→→→→→→ The Person called 311|911 →→→→→→→→→→ The Officer Arrested Me | The Officer Helped Me | Obligations of Doctor|Officer
Arrest | Do You Agree that the Officer has to help Me before an Arrest[Y|N][T|F]
Arrest | Disabled | I am [Injured|Disabled]
Arrest | This Person did not Help Me ________________
Arrest | This Person did not Help Me ________________
Arrest | This Person did not Help Me ________________
Arrest | This Person did not Help Me ________________
Arrest | This Person did not Help Me ________________
Arrest | This Person did not Help Me ________________
Arrest | This Person did not Help Me ________________
Was this Person Your: Friend | Family | Doctor | Officer | Nurse | Social Worker | Marriage Counselor | Other Friend | Other Doctor | Respondant to Emergency | Attorney
Did Your Attorney Agree The Process of Arrest to Involuntary Medication[Y|N] →→→→→→→→→→ Arrest | This Person did not Help Me ________________
Write Down ALL THE NAMES OF ALL THE PERSONS THAT DID NOT HELP YOU DURING ARREST AND INVOLUNTARY MEDICATION
Arrest|Does Your Attorney [Believe in Torture[Y|N][Involuntary Medication[Y|N]Retributive Punishment with Drugs[Y|N]
Write Down ALL THE NAMES OF ALL THE PERSONS THAT DID NOT HELP YOU DURING ARREST AND INVOLUNTARY MEDICATION
Did Your Mayor|District Representative|District Attorney|District Judge|Federal District Representative| Federal State Representative
Arrest | This Person did not Help Me ________________
Does the [Mayor|District Representative|District Attorney|District Judge|Federal District Representative| Federal State Representative] Believe in Torture|Involuntary Treatment|Civil Arrest
Did Your Attorney Discuss with You the Difference between a Civil Arrest a Want a Persecution a Criminal Arrest a Want a Crime
Did Your Attorney Discuss with You the Difference between a Clinical Trial and an Experimental Treatment
Were You Injected as a Consequence of an Arrest
Were You Informed During the Course of Your Life that You Could suffer an Assault Injection as part of an Arrest
Why Did Your Public Health Official did not Run a Commercial of Involutary Treatment Fake Medicine in the 1900 1910 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010 2020 or circa 1400 1500 1600 1700 1800
Does Your Attorney Have an Interest in Running for Political Office?
Does Your Attorney Have an Interst in Constitutional Law
Does Your Attorney Believe in the Constitutional Ammendments or where the Ammendments written Before the Considerations to The Formation of The United States?
Does Your Attorney Separate Clinical Trials with Experimental Drugs, Torture, Experimental Treatment with Mood Drugs
¿What are the Entire Beliefs of Your Attorney or is Your Attorney a Scientist
¿Are new beliefs endangering your Constitutional Rights?
¿Are new beliefs endangering your Constitutional Rights?
¿Are new beliefs endangering your Constitutional Rights?
¿Write Down All the Atrocities executed under a Claim of Civility or Criminality
Prohibited Transitions in Civil to Legal Law Historical References
¿What are the Derivationals of Law Principles to Which Medicine and Law are Based from?
AMENDMENT 1
AMENDMENT 2
AMENDMENT 3
AMENDMENT 4
AMENDMENT 5
AMENDMENT 6
AMENDMENT 7
AMENDMENT 8
AMENDMENT 9
AMENDMENT 10
AMENDMENT 11
AMENDMENT 12
AMENDMENT 13
AMENDMENT 14
¿Were You Pushed to Take Drugs or are You Hypochondriac or are You Convinced that a Drug Treats Your Belief of a Disorder or are You Truly Ill?
¿How Do you Know You are Truly Ill?
¿How Do you Know You are Truly Ill?
¿How Do you Know You are Truly Ill?
World Wide Ill | State Ill | Nationally Ill | District Ill
¿How Do you Know You are World Wide Truly Ill?
Assault
Does Your Attorney Believe in the Types of Assault or does the Person Know Assault or is there a Historical Change in what Assault is to Benefit a Group of Persons with Interest
Atrocities involving Redefinintions of Assault
Write Down ALL THE NAMES OF ALL THE PERSONS THAT DID NOT HELP YOU DURING ARREST AND INVOLUNTARY MEDICATION
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
Did You see it on Television or in a Movie
Why are Your Personal Recording Devices Removed from Your Posession to Enter a Hospital
Write Down ALL THE NAMES OF ALL THE PERSONS THAT DID NOT HELP YOU DURING ARREST AND INVOLUNTARY MEDICATION
Still Not Convinced then You have an Interest that is Easily Discernible from Healthy Medicine
Send the Letter to yerai@syntheticforest.com
Thousands of Years of Civil Arrest are Under the Control of Abusive Persons Wanting to Touch You
Who were those who favored Civil Arrest to determinations of insanity under a burden of proof of partiality during the course of science
What are the Burdens of Proof
51|49
50|50
100|0
Opinion of Fraud Medical Practitioner
Preponderance of The Evidence
Standard of Proof of 51|49 Clear and Convincing Evidence[T|F]
Stand of Proof Beyond Reasonable Doubt
Call Us at 19394564949
Write Down ALL THE NAMES OF ALL THE PERSONS THAT DID NOT HELP YOU DURING ARREST AND INVOLUNTARY MEDICATION
Write Down ALL THE NAMES OF ALL THE PERSONS THAT DID NOT HELP YOU DURING ARREST AND INVOLUNTARY MEDICATION
Write Down ALL THE NAMES OF ALL THE PERSONS THAT DID NOT HELP YOU DURING ARREST AND INVOLUNTARY MEDICATION
Write Doen ALL THE NAMES OF PERSONS THAT BELIEVE IN INVOLUNTARY TREATMENT INSANITY DETERMINATIONS
Include References
Include References
Include References
Include References
Include References
FAKE MEDICINE QUESTIONS TO ASK YOUR DOCTOR
FAKE MEDICINE QUESTIONS TO ASK YOUR DOCTOR
FAKE MEDICINE QUESTIONS TO ASK YOUR DOCTOR
FAKE MEDICINE QUESTIONS TO ASK YOUR DOCTOR
FAKE MEDICINE QUESTIONS TO ASK YOUR DOCTOR
| Fake Medicine | Questions to ask Your Doctor | USC24 42USC Limited
Were you refered to Personal Information or do you know Personal information antecedent to a hospital visit
Who am I in Your System | consumer or patient or trial subject
Belief over Science and Medicine
¿Does a Molecule Correct Visual Discrimination?
¿Does a Poison Correct Visual Discrimination?
¿Does a Venom Correct Visual Discrimination?
¿What are the Fundamental Scientific Principles defining Medicine?
¿Is a Doctor a Scientist or Different from a Scientist?
¿Was Belief involved in the Process of Administering a Drug Intravenously?
¿Do You examine Visually or Through Testing?
FAKE MEDICINE | VISUAL DISCRIMINATION
FAKE MEDICINE | VISUAL DISCRIMINATION
FAKE MEDICINE | VISUAL DISCRIMINATION
FAKE MEDICINE | VISUAL DISCRIMINATION
FAKE MEDICINE | VISUAL DISCRIMINATION
¿What tests did you run to determine a disorder or illness before the visit?
¿What is Consent?
¿Did the Doctor Touch the Person without Consent?
¿Did the Doctor Touch the Person without Consent?
¿Did the Doctor Touch the Person without Consent?
¿Did the Doctor Touch the Person without Consent?
¿Did the Doctor Touch the Person without Consent?
¿Did the Doctor Touch the Person without Consent?
¿Did the Doctor Touch the Person without Consent?
¿Did the Doctor Touch the Person without Consent?
¿Did the Doctor Touch the Person without Consent?
¿Was the Person Transported without Consent?
Constitutional Law | Visual Discrimination | Racism | Exploitation of the Poor and the Homeless | Human Experimentation
Systems of Health Care | Limitations of Medicine | Information Management | Belief in the Transfer of Information | Human Experimentation
Systems of Health Care | Limitations of Medicine | Information Management | Belief in the Transfer of Information | Human Experimentation
Systems of Health Care | Limitations of Medicine | Information Management | Belief in the Transfer ofInformation | Human Experimentation
¿Was an Emergency Declared to Touch the Person without Consent?
¿Was is an Emergency Declaration? 311|911 Disasters
¿Was an Emergency Declaration Exploited to generate patients in the hospital?
¿Was is Grave Disability, Disability, Injury, Promissory Estopel, Partial Liability, Denial of Service
Who are the Persons interested in Converting an Injury, Illness, Disability to an Exploitative Abusive Emergency without Consent
_____________________________________________________________________________
Write the names of the Persons interested in Converting an Injury, Illness, Disability to an Exploitative Abusive Emergency without Consent
Diagram Flow Here | Decisional Matrix
Diagram Flow Here | Emergency Personnel
Diagram Flow Here | First Responders
Diagram Flow Here | Emergency Doctors
Diagram Flow Here | Law Officers, Custodian, Parents, Family, Friends
Diagram Flow Here | State Officials
Diagram Flow Here | Board Officials
Diagram Flow Here | Attorneys
Diagram Flow Here | Persons
¿What are Irreversibilities?
¿What is Human Trafficking for Medical Practice? Transport of a Person from one Place to Another Place for a Medical Treatment without Consent.
¿Are the Persons interested in Interpreting Law to Occupy Government Interests-Offices
¿Was the Person Forced to Take a Drug without Consent?
¿Was the Person Forced to Take a Drug without Consent Unconscious?
¿Was the Person Unconscious?
¿Is Unconsciousness redefinable or has it been known for thousand of years?
¿What is a Civil Trial for Involuntary Medical Treatment?
¿What is the Civil Code?
¿How many persons are involved in the care of a Patient?
¿Does the Doctor know of The Arrest to Treatment pipeline?
¿Did the Doctor prevent the Patient from Leaving the Hospital? To the Family of the Patient.
¿Did the Doctor prevent the Patient from Leaving the Hospital? To the Nurse.
¿Did the Doctor prevent the Patient from Leaving the Hospital? To the Physicians Assitant.
¿Did the Doctor prevent the Patient from Leaving the Hospital? To the Social Worker.
¿Did the Doctor prevent the Patient from Leaving the Hospital? To the Security Officer.
¿Describe in Your own words what services or treatment were given and in what order?
Open the Book of Torts or Torture.
¿Arrest Seclusion Transport of a Person without Consent is a Crime?
¿I was't finished asking the Questions?
¿Describe how you encoutered the Person, what was the knowledge antecedent or precedent to treatment?
¿Describe how you encoutered the Person, what was the knowledge in releasing the person from captivity?
¿Did you document your interaction with the person?
¿At what moment did you start and end documenting the interaction?
¿Was the Interaction part of a Protocol or was it in Your Personal Character that you administered the Protocol?
¿What is a Patient Advocate and who does the Patient Advocate work for?
¿How much time was the Another in Presence of the Victim.
¿What is a Neurological Test?
¿What are the Metrics of a Neurological Test?
¿Is Belief involved in Neurological Testing?
¿I wasn't finished asking the Questions?
Send Letter
TASK FORCE ON FAKE MEDICINE
Contact FBI Headquarters
FBI Headquarters
935 Pennsylvania Avenue, NW
Washington, D.C. 20535-0001
(202) 324-3000
Office of the Inspector General
https://oig.hhs.gov/fraud/report-fraud/Send Letter
NEUROSCIENCE TO BANKING TRANSITION
SIXTH NOTE LONG TERM EFFECTS: MUSCLE MEMORY:
+++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
THE SYNTHETIC FOREST FOOD AND WINE REVIEW: anything you can eat withing the forest... What is not a Forest?
THE SYNTHETIC FOREST FOOD AND WINE REVIEW: anything you can eat withing the forest... What is not a Forest?
THE SYNTHETIC FOREST FOOD AND WINE REVIEW: anything you can eat withing the forest... What is not a Forest?
Obtenir les meilleurs conseils, d'informations, de la nourriture, des ustensiles de cuisine et les techniques ici au SSSFFF.
Hae paras neuvo, info, ruoka, keittiövälineet ja tekniikoita täällä SSSFFF.
SSSFFF will review any Restaurant, Dinner, Lunch Box, Cart, or a la Carte. Do you seek a review of your restaurant? Write to us at yerai@syntheticforest.com
Read Below our Food and Wine Guide: Now, Are you Hungry, are you Thirsty? // SSSSFFFF will branch all world cooking into a single place.
These are All the Measurements you Need...
Measurements Table | |||
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US | INTNL | USA | FLUID Oz |
1Cup | 237 ml | 2 Cups | 8Oz |
1Quart | 946 ml | ||
1Gal | 3.785L | ||
Jigger | 1.25Oz | 1Oz-2Oz | |
1Tbsp | 3Teaspoons | ||
1Oz (s) | 28g | 4Tbsp | |
1Pound | 454g | 1lbm | 16Oz |
Conversions in Cuisine
Meat Temperatures SSSSSFFFFF | |
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Meat | Temperature (F) |
Beef Rare | 140 |
Beef Medium | 160 |
Beef Well | 170 |
Turkey | 180 |
Chicken | 180 |
Lamb | 145 |
Octopus | 130 |
Shrimp | 130 |
Conch | Pressure Cook |
WORLD CUISINE MENU |
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Region | Country | Type | Links / Recipes |
Pacific | Chinese |
Sichuan Fujian Hunan Cantonese Zhejian |
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Japanese | Kaiseki Vegetarian |
http://www.kitchen-theory.com/2014/01/10/kaisekidining/ Sashimi: Pierced Body Sushi Rice Bowls Tempura |
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Canadian | Acadian French | Eastern Canada Central Canadia Western Canadian Smorgasbord and Julbord |
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North American | Bourbon & Creole Soul Food Native American |
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Brisket a la BBQ: Brisket Rub Ingredients: Rub Recipe 1:
More Rub Recipes Here: Rub Recipes Apple Pie Eggs Benedict::
Hollandaise Sause 10 Tbsp unsalted butter
Jumbalaya: Cajun/Creole bell peppers, onion, chicken, sausage, shrimp, crushed tomatoes, broth, celery, rice, and stir continuously. Cover and let it simmer on medium-low for 30 minutes, until the rice is cooked. |
Central American | Mexican Nicaraguan El Salvador Honduran Costa Rican Panama Guatemala |
Aztec Maya-Lenca |
Tamales Plantillas de Maiz Tacos Sopas Mariscos Carnes Arroz |
South American | Colombian Peruvian Chilean and Argentinian Bolivian Honduran |
Andine Valle Cauca Altiplano |
Feijoao Pico de Gallo Bandeja Paisa Articucho Asados https://cookpad.com/es/buscar/remolacha
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Italian | Napolitan Sicilian |
Linguini a la Pesto Sauce: garlic, 2 cups of greens (basil, parseley, romero), 1/2 cups pine nuts, olive oil, 4garlic cloves, 1/2 cup olive oil, for 1pound of linguini pasta. If you don't have pine nuts available use a bit of nutmeg. Gnochi de Yuca. Notes on Pasta. Tomato Sauce |
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Caribbean |
West Indies Cuba Haiti Republica Dominicana Puerto Rico Granada Guadeloupe St Thomas St Kitts St Vincent Aruba St Thomas St John St Croix Tortola Virgin Gorda Anegada Aguilla Saint Martin /p> Saint Kitts Nevis Barbuda Antigua Montserrat Dominica |
Postres: Arroz con Dulce Lechon Asado: recipe: add olive oil, salt, ground black pepper, cumin, culantro, fresh recao, and mix as a paste. The key in making a buen Lechon Asao is to tajar el lechon bien tajao. Also be sure to marinate the pernil in salt and water at least one full day. Use a regular brine concentration. Avoid any citrics or sweets in this recipe. Broil and then lower heat. The Lechon takes a long time to cook evenly, and is generally eaten above medium well, to well done. If you marinate and season the Lechon properly the meat will not end up dry. Promise! Pasteles de Yuca: Pasteles is a broad technique of enveloping foods in a root mash mix. In mexico a corn paste is used to make tamales. In the caribbean platanos, yucca, name, yautia, and batata , the common roots are blended in different proportions and stuffed with any meat. Many variations add acid olives, peppers, sweet raisins, or chickpeas. The key to the pasteles artistry is the enveloping and wrap-tying in platano leaves. Pasteles are tied in pairs called yuntas and take 30-40 minutes to boil in high. PLEASE DON'T ADD KETCHUP. It is a common disagreement between pasteles lovers to include the ketchup. I know you'll agree in the purest form of this great dish.
Cortes de Carne Caribeños: Pernil, Churrasco, Chuletas. Fricase de Conejo El Mofongo Perfecto: ¿Has probado dos mofongos perfectos? Altamente probable que se hallan hecho con detalles diferentes. Mantequilla vs Aceite de oliva, Frito vs Hervido, Con ajo o con chicharron... hay variedad en el mofongo al igual que en el platano. Proximo: como hacer el mofongo perfecto.... Que es verdaderamente caribenño sin una salsa: Aqui comenzamos a experimentar con bases de salsa. La primera: Salsa dulce-picante de Mango: 4 ajos, 1/2 cebolla, 1/4 barra de mantequilla, 2cdas de limon, 1/2 cda de rayadura de limon, 2cdas de cilantrillo. Mezclar bien en una licuadora. Puedes anadir para variar trozos de gengibre o licuar con vino blanco. Decora con rayadura de limon, cayenne o zanahorias. Sirve a mas de 6 personas. Usala como dip, marinado, o salsa base. Que la disfrutes. Sustituir Salsa de Tomate por Pasta de Tomate? |
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Indian | North South East West Gujarat, Maharashtra and Goa |
http://www.theculinaryscoop.com/2011/02/history-of-indian-cuisine/ http://www.indiacurry.com/faqhints/traditionalindianmeal.htm India is extremely large and its cuisine is a broad spectrum from vegetarian to coastal with English , Muslim, Portuguese and Endemic Influences. SSFF will name a couple of spices and dishes you should at least try many times. Ingredients: saffron, pured nuts, coconut, curry, Naan bread, nargisi kaftas (meatballs), biryani (layered rice and meat), rogan josh...Dosa (rice pancakes), Idli (steamed rice cakes), Many different types of Chutney (chutney is an Indian version of sofrito/sauce in Latincountries. sort of a base flavor composed of many spices). Plates and Recipes: dry-cooked Kebab (Tandoori Jhinga, Chicken Tandoori, Shami Kebab, Seekh Kebab, Paneer Tikka, Tandoori Aloo, Murgh Malai Kebab) Dal Bukhara (creamy black bean soup) deep-fried foods (Samosa, Pakora) Gajar Halwa (Carrot Cake) and Kheer (Rice pudding). |
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Vegan and Vegetarian | Turmeric Rice 1.5 cups of rice, 2 tsp turmeric, 2 garlic cloves, 1/2 yellow onion, 2 inches of ginger, 2 cups of vegetable broth per cup of rice, 2 tbsp of oil. 5 inches of carrot natural antiseptic and antibacterial agent anti-inflammatory, anti arthritis and rheumatoid arthritis detoxifies the liver; shown to be affective in fighting Alzheimer’s ; natural painkiller may help in weight management; used to treat depression; used to treat multiple cancers antioxidantcan be used as a Saffron substitute Arroz Verde: Many Latin countries have this recipe involving the green spices of tropical caribbean cuisine. Green color is brought about cilantro, perejil, romero, oregano, and spinach. This rice's green hue can be from light to very heavy green. Here's a recipe: per 3 cups of rice, use two handfuls of cilantro and two other of perejil, add a tablespoon or two of romero (slight green and bitter hint) add 3 garlic heads and half an onion into a blender. Boil rice as you would but substitute water for broth. Add 3 tablespoons of olive oil in the blender and blend until a watery paste results. Add the paste to the rice when cooking and be sure to mix as the greens float. In the end it would be necessary to mix the green layer up top. SSFF takes more than 40 minutes to set the rice. The longer you let the rice set at low heat the looser the grain will be. Serves 8-15 persons. Enjoy. |
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Comercial Blends | Ball Park Food Carnaval Buffet |
Take 8 pounds of carne molida. 2 cans of beer. Put in a bowl and cover the entire surface of the bowl with a salt pepper mix, visibly cover. Add the beer and mix with your hands. Add 1/2 an onion per pound of meat OR add onion until the meat mix is visibly constituted with onion. Take a full ramo de cilantrillo and cut in small pieces, not too small. You can leave the cilantrillo in leave sized size. Mix by hand. Marinate in the beer for 1 full day. During this time the meat will absorb all the juice you add to it. So if you would like add another beer or until you start seeing meat to separate in its consistency. Before cooking, remove all juice. Add 2 eggs to the meat and mix by hand. Then enjoy the best burguers you'll ever enjoy. Alter the recipe by adding 1 tbs of red pepper per pound. Also add more culantro, peppers, recao, romero and lemongrass to taste, to make a green burguer. Serve with two couple of cups red wine and a glass of water. |
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Iberian Peninsula | Portuguese Spanish |
Andalusian Aragonese and Navarra Asturian Basque Canarian Extremadura |
Bacalao... recuerda desalarlo mediante remoje en agua. Guarda un poco del agua para la salsa. Paella: Valenciana, de Carne, de Mariscos... |
Pastas | Global Pastas | Pastas may have been communicated through cultural trips from earlier than 13th century Chinese to the Italians to the World. Below are several basic recipes to enjoy your pasta: http://www.internationalpasta.org/ French Onion Pasta: Medium Shells, 300ml french Onion Consome, 1 cup of diced peppers, 4 garlic heads, 3 leaves of oregano brujo, 1/2 onion or 3 small shallots, |
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Italian | Italian | Italian | Tomato Sauce: 800g tomatoes or ripe fresh fruit Boil tomatoes for a minute, until the skins split. Peel skin, then chop. Heat the oil in a medium saucepan on a medium-low heat and add the chopped onion. Soften onions until translucent. Stir in the garlic and cook for another two minutes. Tip in the tomatoes, and break up with a wooden spoon if necessary, then add the sugar, vinegar and the STEMS of the basil, reserving the leaves. Season. Bring to a simmer, then turn down the heat and simmer for 45 minutes, stirring occasionally, until thick. Test the seasoning, add the basil leaves, roughly torn, and drizzle in a little extra-virgin olive oil if you like before serving. |
French | Mediterranean | To go: Panini, Baguette French Onion Soup: 1/2 cup unsalted butter, 4 sliced onions, 4 garlic cloves, 4 bay leaves, fresh chopped oregano, salt and pepper to taste, 1 cup of red wine, 3-4 tablespoons of flour, 2 quarts of beef broth, Gruyere optional. |
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Greek | Greek | Olive Oil, Citrics, Harina | Lemon Basil Shrimp and Pasta |
Turkish | Turkish | Turkish | Baklava, Menemen, Kuzu Tandır, Pide Ayran, Raki , Salep, Tavuk (Chicken Breast Dessert!), Lamacun |
Kosher | Kosher | Kosher | Kosher recipes: |
Islamic and Arab | Lebanese Arab |
Sefardi Askenaz Mustard, Azafran, Curcuma, Garlic, Curry Cinamon, Pickels, Onion, Citrics |
Hummus: [16oz of garbanzos, 1.5 tablespoons tahini, 3-5 tablespoons of lemon juice (1-2 lemons), 1/2 tablespoons salt, 2 tablespoons olive oil, 1-2 tablespoons chipped cilantrillo. 2 garlic heads, 1/4 cup of water or garbanzo liquid.] Blend all ingredients until texture is heavy creamy. Dress with chili pepper and olive oil, cilantro and chopped onions, sparkle with lemon juice to taste.
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African | Mediterranean Egyptian Ethiopian |
are you in the African Continent? Write to us @ yerai@syntheticforest.com We would like to learn ways to make African dishes. |
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Russian | Russian Salad Borscht Blini Shashlik Pirozkhi Stroganoff |
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Scandinavian | Norwegian Swedish Finnish |
SSSFFF is looking for an intro into Scandinavian food. Write to US! |
DRINKS WINES SPIRITS DISTILLATES WITHIN THE SSSSSSFFFFFF | |||
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Pacific | Chinese |
Fermented Millet Fermented Rice Fermented Grape Fermented Sorghum Baijiu Huangjiu |
Write to us to understand the current trends in Chinese Cuisine @ yerai@syntheticforest.com What are Chinese Flavors, Spices? |
Japanese | Sake Teas |
http://nihon-ichiban.com/100-drinks-from-japan/ Pearl Sake Black Tea |
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Canadian | Acadian French |
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http://www.canadianliving.com/recipe-directory/course_meal_type/drinks_alcohol.php |
North American |
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Central American | Mexican Guatemala Honduras Nicaragua Costa Rican Panama |
Salsa Mole negro, rojo, poblano Horchata Birria Tasajo |
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South American | Colombian Peruvian Chilean Argentinian |
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FERNET & COLA(ARGENTINA)CAIPIRINHA (BRAZIL)SINGANI (BOLIVIA)ZHUMIR (ECUADOR)PISCO (PERU/CHILE)CLERICO (URUGUAY) |
Caribbean |
West Indies Cuban Dominican Puerto Rican Jamaican |
Rum, Rum, Rum, RUM New: Caribbean Craft Beers |
Piña Colada: 2part Bacardi, 1part Coconut Cream, 3parts Pineaple juice.1 cup of ice per 6 oz of mix. The viscosity of the mix can be lowered with added ice. Texture and feel can be changed with ice quantity. Most people enjoy Pina Colada between a frozen and a daiquiri, in that sweet middle spot. Normally the Coconut Cream comes in a 1.75 cup can. So use 6 oz of Pineaple juice. Add the Bacardi for flavor. 2oz |
Indian | Indian Vodka, Indian Whiskey, Sura, Meraya, Majja |
http://www.vegrecipesofindia.com/recipes/beverages/
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Comercial Blends | Ball Park Food Carnaval Buffet |
Where's the best Ballpark Beer? Where are the best streets to hang out out after a game? Special Drinking Events |
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Iberian Peninsula |
Portuguese Spanish |
North to South | Sangria Andrajos White Sangria RecipeWhite Sangria is made with white wine instead of red wine. Ingredients:
Directions:
Tinto de Verano RecipeTinto de verano translates to red wine of summer. This drink is served throughout Spain during the long, hot summers. While it is similar to sangria, it has less alcohol; this makes it a much better drink to sip while sitting in the sun. Ingredients:
Directions:
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French
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Mediterranean | Vin du Region | |
Mediterranean | Greek |
Kolokythoanthoi Avgolemono Fakes Kleftiko Revithia Diples + Loukomades
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African | Mediterranean Egyptian
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Russian
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Black Russian | http://www.expatica.ru/leisure/dining_cuisine/Food-and-drink_-Russian-cuisine_15730.html | |
Scandinavian | Norwegian Swedish Finnish |
Blue Smurf | |
Spice List Especias kruiden
koření
krydder
मसाले
épices
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Black Pepper / Pimienta Negra Oregano / Oregano Cilanter / Cilantrillo Ajo / Garlic Sage / Salvia Thyme / Tomillo Paprika / Paprika Achiote / Achiote Cinnamon / Canela Basil / Albahaca Capers / Alcaparra Allspice / Pimienta Gorda Anise / Anís Bay Leaves / Laurel Chamomile / Manzanilla Caraway / Alcaravea Chives / Cebolleta Chervil / Cerafolio Peppermint / Menta Poppyseed / Adormidera Rosemary / Romero Saffron / Azafrán Savory / Saturega Mustard Seed / Ajonjolí Spearmint / Yerba Buena Tarragon / Estragón Thyme / Tomillo Tumeric / Cúrcuma Vanilla / Vanilla Wintermint / Axocopaque? Ginger / Jengibre Marjoram / Mejorana Mustard / Mostaza Nutmeg / Nuez Moscada Onion / Cebolla Oregano / Orégano Paprika / Pimentón Parsley / Perejil Cardamom / Cardamomo Cloves / Clavo Comfrey / Confrey Coriander / Cilantro Cumin / Comino Dill / Eneldo Fennel / Hinojo Fleur de Sel Kosher Salt Grain Salt |
http://www.whfoods.com/genpage.php?tname=foodspice&dbid=72 SPICE MIX TREND 1: Olive Oil + Garlic + Black Pepper + Onion + Oregano. Substitute Salvia for Oregano.... SPICE MIX TREND 2: Ginger + Olive Oil SPICE MIX TREND 3 SPICE MIX TREND 4 SPICE MIX TREND 99: Write to us at yerai@syntheticforest.com SPICE TIP: SUGAR SENSORS sugar sensors in our mouths detect glucose triggered by sodium which alerts the cell to register sweetness. http://www.ncbi.nlm.nih.gov/pubmed/21450125 SPICE TIP: HUMIDITY: Increase in Humidity means the salt may contain higher concentrations of Magnesium, Calcium, Nutrients. Fleur de sel. SPICE TIP: BOIL and STRAIN: Flaking for Fleur de Sel |
Food and Drink Recipes | |||
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SOUP | Onion Soup | Take olive oil, butter, and heat until mixed. Cut 6 sweet onions and 4 garlic heads into Julienne cut and place in pot. Add salt and pepper, cook until onions are turn transparent. Add 3 tbsp of wheat flour to make a roux. Add 2 Liters of beef broth (substitute a cup of broth with white wine) to pot and top with rosemary, oregano, cebollines, any of your choice of herbals. Cook 25-30 minutes covered at low heat. Taste onions to ensure they are well cooked. | |
KNOCKOUT DRINKS | KNOCKOUT DRINKS | KNOCKOUT DRINKS
Absinthe [45% - 72% Alcohol]Bacardi 151 [75.5% Alcohol]Devil Springs Vodka (80% Alcohol]Pincer Vodka [88.8% Alcohol]Bruichladdich X4+1 Quadrupled whisky [92% Alcohol]Everclear [75% Alcohol]Spirytus Rektyfikowany [96% Alcohol]
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MULTI LAYER SHOTS |
MULTI LAYER SHOTS |
Alien Brain HemorrhageIf you think the idea of severe brain injury sounds like a good way to start the weekend, then you'll love the Alien Brain Hemorrhage! It's even worse than a regular, old, human brain hemorrhage, because it's from space! And we know, because of science. 1 oz. Peach Schnapps Pour the peach schnapps into a shot glass. Layer the Irish cream on top. Finally, add the drops of grenadine to the center of the drink, until it passes through the cream. Voila! --------------------- Lava Flow1 ounce coconut syrup Blend all ingredients except strawberry puree. Pour into a cocktail glass and garnish with strawberry puree. --------------------- The American Flag1/2 oz. Grenadine In layers, pour the grenadine then the crème de cacao and finally the blue curacao into a cordial glass. --------------------- The Jellyfish1/2 oz. Crème de Cacao Pour in layers the white Crème de Cacao then the amaretto and finally the Irish cream in a shot glass. Add 3 drops of grenadine in the center of the shot. --------------------- The 747Khalua, Frangelico, Baileys... almost an Orgasm... 1/2 oz. Coffee Liqueur Pour in layers: #1 Coffee liqueur #2Hazelnut liqueur #3 Irish cream. |
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SAKE | SAKE | SAKE | SAKE: Como hacer SAKE Notes on Fermentation Beer, Brewing Carbonation, Maturation, Sinking and Topping, Top vs Bottom vs Cold vs Hot Fermentation Top Bacteria Strains. soon @ SSSFFF |
BUYING ALCOHOL | BUYING ALCOHOL | BUYING ALCOHOL | https://www.abarabove.com/podcast/mtp-69-mastering-buying/ |
PASTA | PASTA | PASTA | PASTA SHAPES |
Pasta Shapes | |||
Pizza | Pizza Dough | Do you have any good tips in making the Pizza Dough? Write to Us. |
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  Fetuccini Alfredo |
Fetuccini Alfredo | Melt butter in a medium, non-stick saucepan over medium heat. Add cream cheese and garlic powder, stirring with wire whisk until smooth. Add milk, a little at a time, whisking to smooth out lumps. Stir in Parmesan and pepper. | |
Brisket | Brisket | Falda o Pecho de Res Al Horno DRY RUB Preheat the oven to 350°F. |
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SEAFOOD | SEAFOOD | SEAFOOD | |
SSSFFF Shrimp | Shrimp | ||
Shrimps Scampi | INGREDIENTS
Heat a sauté pan on high heat then reduce to medium high heat.Swirl the butter and olive oil into the pan.After the butter melts it will foam up a bit then subside. If using unsalted butter, sprinkle a little salt in the pan. Stir in the slivered garlic and red pepper flakes. Sauté the garlic for just a minute, until it begins to brown at the edges, then add the shrimp. Add the wine and stir to coat the shrimp with the sauce of butter, oil, and wine. Move the shrimp so they are in an even layer in the pan. Increase the heat to high and boil the wine for two to three minutes. Stir the shrimp and arrange them so that you turn them over to cook on the other side. Continue to cook on high heat for another minute. Remove the pan from the heat. Sprinkle the shrimp with parsley, lemon juice, and black pepper, and toss to combine. Serve as is, or with crusty bread, over pasta, or over rice (for gluten-free version). |
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Salmon | Salmon Recipes MARINATING SALMON TIPS Lemon Marinade:
Soy Sauce Marinade:
Sauce:
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Octopus Squid |
Pulpo y Calamares. What are the best ways to cook Pulpo? Grilled Octopus with Ancho Chile Saucehttp://www.foodandwine.com/recipes/grilled-octopus-ancho-chile-sauce PREPARE THE OCTOPUS Preheat the oven to 300°F. In a large enameled cast-iron casserole, heat the olive oil. Add half of the octopus and cook over moderately high heat, turning, until lightly browned all over, 3 to 5 minutes. Transfer to a plate. Repeat with the remaining octopus. Add the shallots and garlic to the casserole and cook over moderate heat, stirring, until lightly browned, about 2 minutes. Add the pimentón and cook, stirring, until fragrant, about 20 seconds. Carefully add the sherry and bring to a boil. Return the octopus to the casserole, cover and braise in the oven until very tender, about 1 hour and 30 minutes. Let the octopus cool completely in the liquid. MEANWHILE, MAKE THE SAUCE In a medium saucepan, toast the chiles over moderate heat, turning, until fragrant and pliable, 2 to 3 minutes. Add the vinegar, honey and garlic and bring just to a simmer. Remove from the heat and let stand until the chiles are softened, about 20 minutes. Transfer to a blender and puree until smooth. With the machine on, gradually add the grapeseed oil until incorporated. Season the ancho chile sauce with salt. Light a grill or preheat a grill pan and brush with canola oil. Grill the octopus over high heat, turning, until lightly charred all over, about 4 minutes. Transfer to a baking sheet and immediately brush with some of the ancho chile sauce. Serve with the jicama salad, passing the remaining sauce at the table. |
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Clams Almejas |
1 libra de almejas o un poco más (25 almejas aproximadamente.) 3oz. de chorizo ½ taza de vino seco blanco 2 cucharadas de aceite de oliva 1 cebolla blanca 6 dientes de ajo 2 cds cilantrillo Sazon de sal y pimienta. Temperatura mediana alta sofria en orden de espesor: cebolla, ajo. Cocer cebolla y ajo a gusto. El orden de sofreir es importante ya que la variabilidad del sabor entre ajo y cebolla y otros vegetales es grande ya que el calor y el aceite liberan mucho el sabor o si se sofrie poco se puede obtener un sabor mas natural del ingrediente. Tradicionalmente el ajo se sofrie hasta rostizar y lograr la carbonizacion del ajo que le anade caracter al sabor. Añade el chorizo y mueve todos los ingredientes para que la sazón del chorizo se incorpore bien. Sofríe por unos 5 minutos más. Por último agrega el vino y mezcla mientras esperas unos minutos hasta que el olor fuerte a alcohol pase (Reduccion ~2 minutos). Aqui puedes espesar la salsa con una cda de mantequilla. Echa las almejas y revuelvelas 1 vez y las tapas por varios minutos hasta que empiecen a abrir. Luego agrega el cilantro, sal y pimienta y muévelas de nuevo. Decorar. |
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Conch Carrucho |
Carrucho al escabeche: http://www.chefmilani.com/ensaladacarrucho.html#.Vf0KvflViko Ingredientes 1lb de carrucho hervido cortado en trocitos Procedimiento: |
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Mussels |
Mussels | http://allrecipes.com/recipes/439/seafood/shellfish/mussels/ |
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Hamburguers | 100 hamburger recipes, soon! SSSFFF, hungry? | ||
Stuffed Mushroom Burguer | |||
Oak Burn Chili Burguer | |||
Salmon Burguer | |||
Double Burguer with Onion Rings | |||
Hamburguer Toppings | Anything you can fit between a bun is considered a topping. Eggs, Jalapeno, Onions, Peppers, Mustard, Mustard Seeds, Lettuce, then experiment with sweet and salty mix, add peanut butter or jelly and give your burger a bright cool twist. |
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ASIAN | |||
Sushi Rice | |||
Soup | |||
CARIBBEAN | |||
White Rice | Perfect White Rice: 1cup of water per cup of rice. It doesn't matter if the rice is long grain or short. The important detail is that water is covering the level of rice. Bring water to a vigorous boil, add salt 2tbs or to taste. Add the rice and let boil. Watch the rice water level. When the water level starts to disappear and you see pores in the rice, immediately lower the heat and cover. THE TRICK IS IN LEAVING THE RICE STILL FOR AS LONG AS YOU CAN WITHHOLD EATING. The longer you cook the rice Lo mas suelto lo ecuentras. Que lo disfrutes. | ||
Arroz Guisado Arroz Curry Arroz con Almendras Arroz con Coco Arroz con Limon y Cilantro |
There are many different ways to make rice. Guisado or sauted, with Coconut or Curry, Green rice with cilantro, sage, or thyme or any other green spice. The trick with these recipes is to make the sauce or add the ingredient in the key moment. Arroz Guisado: Create the sauce and then add rice. Arroz con Almendras: Crunch the Almonds and add before simmering. Arroz con Coco: Add the coconut milk at the end of the simmering time, mix by hand and let simmer for more time. Arron con Limon: the Lemon can be added before simmering or during the simmering. The longer the lemon stands with rice the more acid the lemon flavor will be. You can add the lemon in the end of the simmering time and cover the pan to simply aromatize the rice. Otherwise lemon flavor will sink in the rice and give it a straight acidic cut. |
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Red Beans Black Beans Pinto Beans Pink Beans |
Cebolla, Ajo, Pimientos, Cilantrillo y Recao, Salsa de Tomate y Caldo de Pollo, Zanahorias o Papas... en menos de 30 minutos... ahhh y un splash de vino blanco a lo ultimo. enjoy. Hey would you like to sponsor this part of the Review? let us know at info@syntheticforest.net |
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Lechon Asado | Salt, Pepper, Oregano, Culantro, Achiote, Olive Oil, Lemon juice, Laurel Leaves... at 450F for a loooong time. Write to us if you want the inner details in making a good one. | ||
Pollo Asado | ¿Sabes cortar un Pollo? Te orientamos rápido. Haz una incisión entre el muslo estirado y la pechuga de pollo. esta incision es para separar el muslo del la cadera. Hazla en ambos lados. El pollo no debe punzarce antes de cocinar. Cocina el pollo y cuando este cocido sácalo del horno. Corta por el mismo corte anterior hasta separar el ala y muslo de la cadera. Toma el pollo por el roto del centro y estiralo lo mas que puedas. Te darás cuenta que si cortas transversalmente en ese plano podras separar las dos pechugas de los muslos y las caderas. (debo incluir fotos). Terminarás con el pecho en un lado y las caderas en el otro. Para picar las pechugas ten un cuchillo bien afilado y corta hasta el hueso por el mismo centro. (aqui me detengo para una aclaración... es como todo animal, tiene hueso en el pecho protejiendo los organos. Hago la aclaración porque, hemos comido miles de pechugas sin saber como se obtienen). Comparte tus técnicas de picar el pollo con nosotros. Escribenos a yerai@syntheticforest.com |
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Mofongo | Freir el platano. Majarlo y luego cubrir con ajo. Hacer mofongo es un Arte! comparte tus recetas de hacer mofongo en: yerai@syntheticforest.com |
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Pasteles | |||
ARABIC | ARAB PAN ARAB MEDITERRANEAN AND AFRICAN ARAB | ||
Hummus | 2 latas de Hummus. Tahini, limon, cilantrillo, pimienta cayenne, aceite de oliva: mezclas todo y yá. Sirve con un toque de limón. Proporciona a gusto. Es asi de facil. Hummus dura no más de 3 a 4 dias en la nevera. |
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Kabab | Lamb, Chicken, Veal, Pork, Beef... | ||
TEA | A section Completely dedicated to the Exploration of Tea flavors and Health Benefits. Lemon Tea Ginger Tea Rosemary Tea : http://www.bodyenlightenment.me/blog/2011/05/remarkable-rosemary-the-benefits-of-herbs-extracts-and-teas/
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TEA TYPES |
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SANGRIA | PUNCH | While there are infinite ways of making Sangria, there are certainly only a good number of ways of making it. We'll give you some basic tips to make the best sangria for most paladar tastes. Not extremely sweet, and enticingly intoxicating punch. |
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SSSFFF | Wines, Juices, Soda Water, Rum, Vodka, Tequila, Lemon, Lots of Ice, Lots of Shaking, lots of sangria. | ||
Long Island | LIIT: Vodka + Tequila + Rum + Gin + Triple Sec + Lemon Juice + Carbonated : Shake WELL | ||
Green Sangria | Based on green alcohol and green spices, Yerba buena, Mint, Peppers, Sage... | ||
Ginger Sangria | Either make Ginger juice or let ginger cuts stand in the refrigerator for at least 10 hours... | ||
White Sangria | White wine, white rum, clear colors, lots of ice... | ||
Rosemary Sangria | Heat water and rosemary until boiling, then simmer for 5 minutes. Cool then strain out the rosemary. Mix with pineapple juice and ginger ale right before serving. | ||
COBBLERS | |||
Sherry Cobbler | First of all know the Types of Sherry before ordering this drink: Amontillado, Fino, Oloroso. 3.5oz of Sherry, 1 tbsp Sugar, 3 Orange Slices. Mix Orange + Sugar + Sherry + Crushed Ice and Shake. Garnish with mint and straw. Varieties of Clobbler with Lemon, Cranberries, Raspberries. Drink it here at the SSSFFF. | ||
DRINKS | DRINKS DRINKS DRINKS DRINKS DRINKS DRINKS DRINKS and Don't Drive, need a cab? info@syntheticforest.net | ||
Bloody Mary |
Garnish with lemon, carrot, celery Vodka, Tomato Juice, Worcestershire sauce, Tabasco, Piri Piri sauce, Beef Consomme, Bouillon horseradish, Celery, Olives, Cayenne, Salt, Black Pepper, Lemon juice and Celery Salt
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Cosmopolitan | Fresh Vodka | 1.5 Vodka, 0.5 Cointreau, 1.0 Cranberry juice, 0.25 Lime Juice, Dress with Zest. Shake thoroughly, strain ice, serve cold. | |
Mojito/Julep | Fresh Citric | 6oz Rum, 4tbsp Sugar, 6 tbsp Fresh Lime Juice, 15 Mint Leaves, Club Soda. Mix all ingredients with ice, serve in a tall rounded glass, top with club Soda. Mystery ingredients: (a hot spice). Julep substitutes Rum with Bourbon. | |
Black Russian | Vodka | Vodka + Coffee Liquor | |
Cuba Libre | Rum | Rum + Coke (sponsors?) | |
Orgasmo | Amaretto+Vodka+Kahlua+Cream | ||
Glow Drink 1 | Glow in the Dark | Pea Flower Tea + Rum Coconut + Blue Curacao | |
Glow Drink 2 | Glow in the Dark | Gin/Vodka + Tonic + Sweet Mix | |
Glow Drink 3 | Glow in the Dark | Blue Food Coloring + Energy Drink + Vitamin B + Rum/Whiskey/Vodka | |
Glow Drinks | Glow in the Dark | Chlorophyll + Guanine + Absinthe + Tonic Water + Club Soda + Food Coloring.... | |
WHISKY | 40-90% alcohol Fermented Grain Mash Aged in Oak (Roble) | ||
Bourbon | Corn Mash >50% corn, Distilled at 160proof and aged at 125. | ||
Scotch | Barley Mash | ||
Rye | Rye (centeno, familia del trigo y cebada) (pumpernickel, knackebrod)(vodka) |
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Irish | From Ireland... we'll wait to go to Ireland to characterize this alcohol. | ||
RUM | RUM | RUM | |
Kiwi RUM | RUM Drink |
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THE BAR | SSSFFF ELEMENTS FOR A BAR |
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Soda Water | |||
Ice | |||
Orange Juice | |||
Grapefruit Juice | |||
Lemon Juice | |||
Cranberry Juice | |||
Triple Sec | |||
BEERS | |||
Porter | |||
Stouts | |||
Bocks | |||
Pilsner | |||
Wheats | |||
Pales |   | ||
Lagers |   | ||
RUM | RUM | RUM | |
Bacardi | Rum | ||
Palo Viejo | Rum | ||
Barcelo | Rum | ||
Don Q | Rum | ||
Ron Crystal | Rum | ||
151 | Rum | ||
Anise Rum | Rum | ||
Amarreto Rum | Rum | ||
Spiced Rum | Rum | ||
Cachaca | Rum | ||
Jagermeister | Liquor | ||
Ginger Liquor | Liquor | ||
Mint Liquor | Liquor | ||
Ron Cana | Liquor | ||
Apperol | |||
Absolute Vodka | Vodka | ||
Smirnoff Vodka | Vodka | ||
Spritz | Apple-Grapefruit Ginger-Lime Apple-Grape 2 oz Prosecco, 1 1/4 oz Aperol, Splash of Soda water http://www.spritzinc.com/test/#/ |
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Khalua | Coffee Liquor | ||
Bahia | Coffee Liquor | ||
Tia Maria | Coffee Liquor | ||
Cafe Granita | Coffee Liquor | ||
Bayleys | Coffee Liquor | ||
Coco Lopez | Mix | ||
Citric Mix | Mix | ||
Kapali | Coffee Liquor | ||
Dewars | Whiskey | ||
White Label | Whiskey | ||
Black Label | Whiskey | ||
Jack Daniels | Whiskey | ||
Cointreau | Liquor | ||
Passoa | Liquor | ||
Brandy | Liquor | ||
Cognac | Liquor | ||
Tanqueray | |||
Oranges | |||
Peppers | |||
Lemon | |||
Matches | |||
Blow Torch | |||
Mixer | |||
Strainer | |||
Sugar | |||
GLASSES |
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Categories: Please see below (from: http://www.dailyinfographic.com/the-different-types-of-wine-infographic):
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Delta | Delta | Delta | Cell | Lens | External Enviroment | Cortex Integration | Instantaneous Motion | The Box Photon
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Eyesight Objectivity |
Magnification Factors |
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Reflexology in Architecture | Astronomical Derivations | Focus Study Limits | Transitions in Eye Detection
Chakra Activation
Potential Energy Surface Study | Liquid Surface Potential
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Public Banking Increases Interests on Deposits at a a Current Rate of [0.0001 0.00001 0.000001] in Low Income Accounts that Contribute the [Fraction] of National Taxable Income, Taxable Land, Taxable Sales.
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19394564949
| Guaynabo Puerto Rico | Montrose Colorado | Brooklyn New York |
Chemistry at SSFF .
Do you need Chemical Analysis or Chemistry Related Technologies? Write us with your questions at SSSSFFFF.
синтетической химии лес домой
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Atomic Structure | ||||||||||||||||||||
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What is an Atom? | The Structures of both Atoms and Galaxies show observable motifs directing the attention of observers to the dynamics of the observable universe, which is Infinite. Are there more Atoms in the Periodic Table that we do not know of? |
When where atoms observed for the first time? What are the earliest conceptions of atomic and subatomic interactions. Particle-Wave Duality. Massless Particles. |
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Electronic Structure, VSEPR | n: principal quantum number: 1,2,3,4 l: 0s, 1p, 2d, 3f orbital. S: 0, P: -1,0,+1 m: for p subshell (-1, 0, 1)... s: spin: angular momentum s p d f 1 2 2 3 3 3 4 4 4 4 5 5 5 5 6 6 6 7 7 |
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Effective Nuclear Charge | #protons - nonvalence electrons. Higher Nuclear Charge = Smaller Atomic Radius. |
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Periodic Trends The Periodicity of Elemental Structure: Electron Affinity vs Electronegativity vs Ionization Energy |
The Periodic table is not a square table ; Atomic Radius increases down a Column and to the left in a Period. Ionization Energy increases to the right in a period and up in a column. Helium has highest ionization energy. Electron Affinity: Increases to the right in a period and up in a column. Generally it increases up in a column, ex Cl vs F Electronegativity: Increases up a column and to the right. FOClNlBrISCH:decreasing order of electronegativity Electron Affinity follows trend of Electronegativity, generally increasing as a more stable structure is formed when an electron is gained. Ionization energy is the energy required to remove an electron from an atom. Electronegativity with respect to an atom in a molecule. Lattice energy is the energy released when a crystal is formed from its constituting ions. e.g. Na+ Cl- → NaCl(s). The ionic bond is stronger as the charges between atoms is larger. Al(OH)3 is insoluble in water because of large lattice energy Acidity increases to the right in a period and down a column. It is related to the stability of the anion. As the size of the anion is increased charge can become delocalized easier. |
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Periodic Exceptions | Cl has higher electron affinity but lower Electronegativity than F because of electron pair repulsion in the valence shell. Transition metal: When d-block elements form ions, the 4s electrons are lost first. Vanadium has a higher melting point than Cr. Generally melting point is increased to the right within a period because of london/induced dipole forces. V:[Ar] 4s2 3d3; V3+[Ar] 3d2 Cr has a half filled d level [Ar] 4s1 3d5 Cu: [Ar] 4s1 3d10 Au: has only one valence electron: Ag: [Kr] 5s1 4d10 |
21Scandium and 22Titanium: 1s2 2s2 2p6 3s2 3p6 4s2 3d1 , 1s2 2s2 2p6 3s2 3p6 4s2 3d2 |
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Bonding | Charge, Ionic and Polyatomic Ions, Ionic Strength; Hydrogen Bond, Electronegativity, NH4+, PO4-3, SO4-2, ate-ite |
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Covalent Bonding | Hybridization, Geometries sp3, sp2, sp | Carbocation has sp2, trigonal planar geometry | ||||||||||||||||||
Hydrogen Bonding: Dipole Moments | FON: A hydrogen bonded to a electronegative halogen can Hydrogen bond with another electronegative halogen. This can occur intramolecularly within short distances, around 1 C-C length. |
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Acid and Bases: Reduction Oxidation Reactions: Lewis Acid, Bronsted Acid, Lewis Base, Bronsted Base, Buffer, K, pK, Strong vs Weak Acids, Titration, Hydrolysis, Electrolytic Cell, Anode Cathode, Galvanic vs Electrolytic Cell, Reduction Potential. Disproportionation |
Arrhenius Acids yield H+. If a substance accepts a pair of electrons to form a covalent bond it is condsidered a Lewis Acid. Reducing Agents: Reductor: Reducer: looses electrons: LiAlH4, H2. Metals act as electron donors giving off ions in solution.Then it is said that the metal has been oxidized. Fe(s) → Fe++ + 2e-. Substances that are oxidized act as REDUCING AGENTS. Reducing Agents are oxidized. Oxidizing Agents are Reduced. Oxidant = Oxidizing Agent = Oxidizer Reductant = Reducing Agent = Reducer. Reducers gain Electrons given by the Reducing Agent that has been Oxidized (donating electrons). LiAlH4 + 4 H2O → LiOH + Al(OH)3 + 4 H2 CARDIO Base: Charge-Atomis size-Resonance-Dipole Induction-Orbital: more negatively charged species are more basic, larger atoms with negative charges are more stable weaker bases, more resonance more stability, sp3 more basic than sp2... |
NADP+ + H+ + 2e- → NADPH NADP+ accepts electrons from water. This is a reduction. NADPH is the reducing agent. NADH IS NOT NADPH. Acidity and Melting Point are not related. Larger atoms are more acid because they can form more stable anions. |
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Redox
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Oxidation: Gain of O, Loss of e-, Loss of H+
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Arrhenius Definition
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Arrenius Acids : Donate H+ Arrhenius Base: Accepts H+ Compounds ionize in solution (water only). |
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Lewis Definition
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Lewis Acid accepts e- pair: Electrophile: Trigonal Planar BR3 with empty p orbital. H+ is a LA. H+ + NH3 → NH4+ . Carbonium is electrophilic thereby a strong LA. Strong Lewis acids are electron deficient. Strong Lewis Bases are electron rich. Lewis Acid Base Pair Lewis Base donates nonbonding e- pair: H-, F-; are nucleophiles |
Basic Amino Acids: Lys, Arg, His. Conjugates of Strong Acid/Base have no effect on pH:
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Bronsted Lowry | Acids increase H3O+, Bases Increase -OH | |||||||||||||||||||
Conjugate Acid/Base Pairs | To find the conjugate base of an acid, take off a H+ HCl is a strong acid. Cl-, its conjugate base has no effect on pH. Acids dissociate completely. The more stable is the anion the more acid is the molecule. NH4Cl: NH4+ is the conjugate acid of weak base NH3 Weak base NH3, conjugate acid NH4+ strong acid. acid + base = conjugate acid + conjugate base |
Strong Acids: HNO3, H2SO4, HCl, HClO4, HBr, HI SuperStrongAcids: HFSO3-SbF5 other scales beside pH are used to measure SSA. Corrosiveness NOT EQUAL to Strength = HF |
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Ka vs pKa | COOH has a pKa of 4 - 5 The lower the pKa the higher the Ka. Low pKa are acidic. High pKa are basic. When pKa and Ka are equal the compound is in equilibrium and the slope of titration curve is linear. |
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ELECTROCHEMISTRY |
ELECTROCHEMISTRY From Nerst to Current Trends
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Electrostatic Energy Lattice Energy kQq/r vs F =k(q1q2)/r^2 ΔU = ΔH - p ΔV Gauss Law: I = EAcos(-) F = qvB sin(-) F = qE |
Coulomb's law k = 9E9 Nm^2/C^2 Electric field lines move out of the positive charge and into negative charges. V=J/C A dipole aligns so that the positive lines are into the negative and out of the positive. The positive end of the dipole will be aligned with the electric field lines. Charge moving in a circle: F = qvB = mv^2/r ; if qvB = mv^2/r the charge is spiralling in. if qvB = mv^2/r the charge is curving. Current Carrying Wires: F = qvB sinθ = (it)vB sinθ = (it)(L/t)B sinθ = iLB sinθ A negative Force means that charges are attracting. |
http://farside.ph.utexas.edu/teaching/em/lectures/node56.html | ||||||||||||||||||
Current |
CURRENT TRENDS: Conventional Current Flow is Opposite to Electron Current Flow. Arbitrarily the current flows out of the short battery symbol into the circuit. The Current in a Parallel Circuit is Split at Ramifications like water flow. The current in a Series Circuit is Steady. What drops is the voltage (like water pressure).
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Resistors in series are linearly additive. They function like one resistor. | ||||||||||||||||||
Electrolytic Cell |
E(cell) < 0, the reaction is spontaneous and happens in a galvanic cell. Faraday's law E(cell) = E(oxidation) + E(reduction) |
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Galvanic = Voltaic Cell | Two pure metals connected by a salt bridge. Oxidized species + e- = Reduced Species Metal cations induce reduction of metals in other cell. So the more positive Oxidation Potential Metal gives off electrons from the Anode to the other metal Cathode. Zn + Cu2+ → Zn2+ + Cu . In a galvanic cell of Zn and Cu electrodes. The Zinc electrodes looses mass as electrons go to Cu2+ and Zn++ goes into solution. |
Ionization Energy increases to the left and down a column. + | ||||||||||||||||||
Difference between Electrolytic and Galvanic Cell | ||||||||||||||||||||
Capacitor | U = (1/2)CV^2 | |||||||||||||||||||
Laws | Ideal Gas, Boyle, Charles, Avogadros: Henry, Raoult, Arrhenius, Hess, Zeroth, First Law, Second Law, Rate Law, Le Chatelier, Faraday, Newton's First, Newton's Second Law, Dalton's Law | |||||||||||||||||||
Kinetic Theory of Gases k = R/Na Partial Pressure, Mole Fraction STP: 0C, 1atm |
Boyles law: PV = k: inverse proportionality P1V1 = P2V2 Charles law: V/T = k: direct proportionality: V1/T1 = V2/T2 Avogradro's Law: V1/N1 = V2/N2 Dalton's Law: p = xP also vi = V * pi/P Henry's law pi = k ci: pi is the partial pressure of the solute. "At a constant temperature, the amount of a given gas that dissolves in a given type and volume of liquid is directly proportional to the partial pressure of that gas in equilibrium with that liquid." Raoult's law: p = p* x; p* is the vapor pressure of pure component. Raoult vs Henry: Henry is more related to solute, Raoult to solvent: When the solvent is in a great quantity the constant of proportionaliy is the partial pressure of the solvent. |
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Real Gas Law, Van der Waals | ||||||||||||||||||||
PRESSURE AND MASS EFFECTS | Molarity: kg / L Molality: mol / L Normality: meq / L Molar Volume at 0C and 1atm = 22.4L/mol |
f = Av
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Mass Effects Return Home | Surface Tension | |||||||||||||||||||
Colligative Equations
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Solubility vs T, P. Osmotic Pressure: Solvent moves across a semipermeable barrier from high concentration to low concentration. The pressure difference across the chambers is the osmotic pressure. Chaotropic agents: increases solubility of non polar. (Alcohol, Urea, Lithium acetate). Denature proteins by increasing hydrophobic solubility. Kosmotropic increase water-water interactions. Stabilizes intermolecular protein interactions thereby preventing aggregation. (Mg2+, Li+1, Zn2+), mostly small positive ions). Ammonium sulfate. |
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Surface Tension |
Mechanical Properties of Liquids |
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Solubility | Ksp All 1A metal salts are water soluble All NH4+ salts are water soluble All NO3--, ChH3O2-, ClO4- , are water soluble. KNO3 SO4 -2 sulfate PO4 --- phophate Complex Ion formation, solubility Common Ion effect Silver salts are insoluble in water with the exception of silver nitrate, silver acetate and silver sulfate. Chlorides Bromides Iodides, are soluble with the exception of AgCl2, PBCl2, HgCl2 |
Base Solubility: Ca(OH)2 is soluble. Group 1 and NH4+ salts are soluble Group 2 MgO, metal oxides are insoluble. Sparingly soluble salts derived from weak acids tend to be more soluble in an acidic solution.Which of the following insoluble salts—AgCl, Ag2CO3, Ag3PO4, and/or AgBr—will be substantially more soluble in 1.0 M HNO3 than in pure water? Answer: Ag2CO3 and Ag3PO4Good Reference: http://chemwiki.ucdavis.edu/Wikitexts/UC_Davis/UCD_Chem_2B/UCD_Chem_2B%3A_Larsen/Unit_IV%3A_Chemical_Equilibria/Chapter_17/17.4_Solubility_and_pH |
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Buffers | Tritration Curve Effect | |||||||||||||||||||
Ksp | Ksp describes Saturated Solutions.
Ksp= [Ba2+][CO32-] = 5.1 x 10-9 |
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Heat Effects Conduction, Convection Radiation, Work, Rankine Scale, Absolute Scale, Conservation, Decay, Half Life |
Enthalpy Hess Bond Dissociation Heat Endo, Exo, Enthalpy, Heat Capacity, Specific Heat, Entropy, Gibbs Free Energy, Spontaneity, Heat of Fusion, Heat of Vaporization Zeroth Law, First Law, Second Law. |
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Heat of Hydration | Thermodinamically favorable. Solvation releases heat. First heat is required (ENDOTHERMIC) to break up an ionic crystal lattice. The hydration step is exothermic. |
Think of Dissolving Salts, is it Exo/Endo Thermic? | ||||||||||||||||||
Heat of Combustion | Energy released when a compound is completely combusted with O2 under 1atm, 298K. Ciclohexane has lowest heat of Combustion per CH2 group. |
Reference: | ||||||||||||||||||
Heat of Formation | Standard States 1atm of gas, or elemental solid. at constant T 298K, P 1atm. Sum of all the bonds broken and all bonds formed from elemental atoms or molecules in their standard state. |
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Le Chatelier | In an equilibrium reaction the mass of a species, temperature, or pressure can shift the equilibrium concentrations to favor an increae of products or reactants. | Reference: http://www.citycollegiate.com/chemical_equilibrium8.htm | ||||||||||||||||||
Spontaneity | ΔG is negative. Standard Reduction Potential is positive E0. ΔG = -RTln(K); ΔG = -nFE |
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Kinetic Effects | ||||||||||||||||||||
Catalysis, Enzymes, | Reaction Order, Reaction Rate Rate Determining Step
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Enzyme-Catalysed Reactions Display Saturation Kinetics. increasing substrate concentration means an increasing rate at which the enzyme and substrate molecules encounter one another. Enzymes lower Activation Energy. Enzymes do not change the Thermodynamics of a Reaction. |
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QUANTUM MECHANICS | Alpha particles: He nucleus: 2 protons, 2 neutrons Beta particles: +/- Beta Decay: neutron decomposes. Beta decay is usually B(-) B(+): Nucleus converts a proton into a neutron and a positron.The positron is liberated. Atomic number decreases. Occurs when the isotope has too few neutrons. B(-): electron is liberated. Atomic number is increased. Neutron is decomposed into electron and proton. Electron is referred to as B particle. Electron Capture EC: Electron meets Proton and is converted into a Neutron. Mass number replicates but proton number is reduced. Element change. Gamma Radiation: Eergy emmtted as Electromagnetic Radiation. |
Alpha particles are very destructive. 4/2. They are quickly absorbed by skin. c = 3(10)^8 m/s |
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Wave Duality, Wave Properties, Amplitude, Intensity, Superposition, Resonance, Diffraction, Refraction, Harmonic Motion, Pendulum, Differential Movement Materials Sciences Solids, Density, Thermal Expansion, Viscosity, Magnetism, Force Direction, Coulomb, Ampere, Field Line, Charge Distribution, Insulation,
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L = I𝛚 → [Angular Momentum] = [Moment of Inertia]/[Angular Velocity]
[Angular Momentum] = L Linear Velocity → 𝛎= r𝛚 Centripetal force F = -mv^2/r Momentum p = mv; m = Δ P / Δ t Impulse I = Ft Hook's law F = -kx |
Momentum is always conserved: in elastic and inelastic reactions momentum is conserved. In Inelastic collisions Kinetic Energy is NOT conserved. Kinetic Energy is lost.
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SOUND | ||||||||||||||||||||
Sound Waves | Transverse Wave: Displacement of medium is perpendicular to direction. A transverse wave can only occur in the surface of a liquid, not in its body. TW can occur in solids. Longitudinal Wave: Displacement of medium is along direction of motion. Sound can be represented as a Longitudinal wave. Light can be represented as a Transverse Wave. |
Δθ = λ / d | ||||||||||||||||||
Half Life | N= No(1/2)^(t/t(1/2)) | |||||||||||||||||||
Current, Voltage, Resistance, Ohms, Resistivity, Capacitance Circuits, Capacitor, Dielectric, Power, Circuits in Series, Circuits in Parallel |
V = IR I = Δ Q / Δ t P = VI = RI^2 RMS I RMS V B = [Ns/Cm] = Force/ ChargexVelocity |
Ohms Law is used to calculate Voltage Drop across a resistor. | ||||||||||||||||||
How do you know the Magnetic Field is Perpendicular to the Electric Field? | ||||||||||||||||||||
Applied Effects —°µ | ||||||||||||||||||||
Hydrostatic Pressure, Surface Tension, Bernoulli's Equation, Flow Profiles | ||||||||||||||||||||
Normal Force, Vectors | Collisions: Perfectly Inelastic p = (m1 + m2) v |
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Radians | Theta = arc length/ radius 1arcsecond=3600radians 2pi/360 = |
Refer to spreading equation of light and sound. The spreading is proportional to the wavelength of the emitted wave over the distance of the orifice of emission. | ||||||||||||||||||
Power | Units: Watts: [W]→ P = VI = V^2 R | |||||||||||||||||||
Energy Work | Units: Joules: [J] | |||||||||||||||||||
Potential Energy | PE=mgh, PEspring=kX^2/2, PEg= -GmM/r ΔPE=qDeltaPHI: electric lines point in the direction of the lower electric field.
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Force | Fspring = -kx | |||||||||||||||||||
Waves | Light, Polarization, Refraction, Diffraction, Doppler Effect | |||||||||||||||||||
Light | Interference, Young's Double Slit, Laser, Color and Energy Angle of Incidence = Angle of Reflection with respect to the normal. The angle is often referred with respect to the Surface. Index of Refraction n = c / v. n1 sin( 1) = n2 sin(2). Internal reflection occurs when light travels from a medium of lesser light speed to greater light speed (greater n to less n) Because the index of refraction of red and blue light is different the eye cannot focus on red and blue light coherently.
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Visualize Water. | ||||||||||||||||||
Magnetism | Direction and force of charge in Magnetic Field. | |||||||||||||||||||
Resistance | Resistance is added in series. | |||||||||||||||||||
Voltage
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Parallel Voltages are equal. Voltage is a Potential Difference V = I R |
Galvanic and Voltaic cells Electrolytic cells drive nonspontaneous reactions. |
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Circuits
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Current, Voltage, Resistance, Resistivity p = RA/L, Capacitance RMS Voltage, RMS current. |
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Capacitor
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Capacitors in series are 'parallel added'
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Optics | (1/f) = (1/i) + (1/o); Magnification: M= -i/o; Focal length (f) is 1/2 radius of curvature: f = r/2; Lens Power: [Diopters] = 1/f Snells law: n sin () = n sin () Concave Mirror: Real (always Inverted) image small, larger to underfined, Virtual larger image Convex Mirror: Virtual Erect smaller image. The Cocave Lenses are Diverging.focal length is (-) for a diverging lens. Diverging Lenses form only Virtual Images. Virtual Images are upright so their magnification value is (+)
Diverging. Convex mirrors and Concave lenses NEVER form Real Images. Real images can be cast on a Screen? |
f is positive for a concave mirror and negative for a convex mirror. All real images are inverted and all virtual images are upright. How does the image of a Concave Mirror change as you move closer? http://mcat-review.org/light-geometrical-optics.php |
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Optics: Eye Correction |
Myope: Nearsighted: cannot see far away. Light focuses in front of retina. Divergent lenses are needed. Hypermetropy: Farsighted: cannot see close. Light focuses behind retina. Convergent lens needed. |
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Converging Lens | http://www.acs.psu.edu/drussell/Demos/RayTrace/Lenses.html | |||||||||||||||||||
ORGANIC CHEMISTRY | ORGANIC CHEMISTRY | ORGANIC CHEMISTRY | ||||||||||||||||||
Nomenclature of Alkanes | 1. Take longer chain 2. Number the carbons of the parent chain from the end that gives the substituents the lowest numbers. When compairing a series of numbers, the series that is the "lowest" is the one which contains the lowest number at the occasion of the first difference. If two or more side chains are in equivalent positions, assign the lowest number to the one which will come first in the name. 3. If chains of equal length are competing for selection as the parent chain, then the choice goes in series to:
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GOOD REFERENCES http://www.acdlabs.com/iupac/nomenclature/79/r79_36.htm http://www.iupac.org/ http://butane.chem.uiuc.edu/cyerkes/Chem104A_BFA05/Genchemref/nomenclature_rules.html |
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Hybridization | sp is 50% s character which is less energetic than p. This results in increased acidity. SP2 Hibridization: Trigonal planar geometry. Free p electron. Nitrogen in a cycle. Nitrogen in a cycle has the free pair projected outside the plane in trigonal planar geometry, sp2 hibridization. SP Hibridization examples: triple bonds. |
Exceptions: BH3 is sp2 hybridized. CO2: sp with 180' |
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Formal Charge |
FC = V- (N + B/2); e.g. NH4+: Nitrogen has a +1 formal charge (5- (0 + 8/2) = +1) Oxygen in NO2- : 6 - (4 + 4/2) = 0 |
Formal Charge of Phosphoric Acid.P=0, hibridized sp3 FC = Valence - (alone bond pairs - half of bonding electrons) 5-(0+10/2) = 0 |
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Degrees of Saturation | (C2n+2 - H) / 2; example BuckyBall C60: (122 - 0) / 2 = 61 Nitrogens count as 0.5C Oxygen does not count. Halogens count as Hydrogens. Nit |
Additional Equations exist that result for degrees of unsaturation. Shortcut: Double bond = 1deg of unsat. 1 triple bond = 2 deg of unsat 1 cyclic molecule = 1 degre of unsat |
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Functional Groups | BP: Alkoxide>Carboxilic acid> Alcohol>Ether>Alkane BP Amines: Amonium Salt>Primary;Secondary, Tertiary Amines basicity is increased with electron donating groups. Secondary amines are stronger bases than primary amines. Imine R=N-H |
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Chirality | Geometric Isomers: cis-trans | |||||||||||||||||||
Stereoisomer: 2^n: Chemical Formula Stereisomeric. R, S | ||||||||||||||||||||
Enantiomer R to S, RR to SS, SR to RS | ||||||||||||||||||||
Diastereomer RS to SS, SR to RR | ||||||||||||||||||||
Optical Activity: +/- indicate physical bend of light. R/S only indicate imaginary rotation. | Diastereomers and Racemic Mixtures are NOT optically active. | |||||||||||||||||||
Isomers | Constitutional Isomers: Ortho ./ Para : Molecular formula Isomeric with different connectivity. Configurational (R), (S): differe in bond configuration. Rotamers: Conformational Isomer. Regioisomer: Different starting material configuration give different structuraly isomeric products. |
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Induction |
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Acidity | S-S-C-P-A-alpha-SP-SP1-SP2-SP3: | "" | ||||||||||||||||||
Resonance | Contributing structures with delocalized electrons in free p orbitals. The contributing stuctures are not equal. The structure that locates the charge in the more electronegative atom is more stable. Resonance contributes to increasing acidity by stabilizing the negative charge of conjugate bases. |
http://goldbook.iupac.org/R05326.html | ||||||||||||||||||
REACTIONS | REACTIONS | REACTIONS | ||||||||||||||||||
Hydrogen | Hydrogen Proton H+, Hydride ion H: -1 | |||||||||||||||||||
Hydrolysis | ||||||||||||||||||||
Heterolytic Hydrogen Cleavage | The electron pair of the bond goes to identical atom. | |||||||||||||||||||
Homolytic Hydrogen Cleavage | each electron of the bond goes to a different atom. Radicals are stabilized by electron donating groups. Peroxides give antiMarkovnikov products with alkenes. | |||||||||||||||||||
Radical Reactions | Initiation Propagation Termination Inhibition Radical Stability: Alllylic and Benzyllic Radical are comparable. Vinyllic Radical has higher bond energy because the double bond in more electronegative. Stereochemical Considerations Br2 vs Cl2: Selectivity; ratio of products |
Good Reference: http://www.mhhe.com/physsci/chemistry/carey/student/olc/graphics/carey04oc/ref/ch10allylic.html http://www.slideshare.net/hussain_761/free-radicals-12023253 |
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Nucleophilicity | Increases going down the periodic table F- < Cl- < Br-< I-; Increases to the left across a period CH3-> NH2- > OH- Nu: are Lewis Bases. Donate protons.
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S1 | Solvent: Polar Aprotic DMSO, DMF, MeCN, Dimethyl Ketone, Acetone: Polar Aprotic Solvents stabilize Carbocation. Polar Aprotic solvents cannot bond with Nu: [Adjust], most stable carbocations. Racemization Likely so result is either a racemic mixture or diastereomer. 3ry>2ry: Carbocation is formed. Reaction Rate = k [electrophile] Weak Nucleophiles Favor Sn1
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Alcohols and Alkyl Halides undergo substitution reactions. | ||||||||||||||||||
Sn2 | Solvent: Polar Aprotic DMSO,DMF, MeCN, Acetone, Polar Protic Solvents favor E2 over SN2. Polar Aprotic Solvents Favor SN2 over E2. STRONG Pointer: Rule Out Possibilities: if you see a protic solvent rule out Sn2... |
References: http://www.masterorganicchemistry.com/2012/12/04/deciding-sn1sn2e1e2-the-solvent/ |
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E1 | Solvent: Hydrogen Bonding Solvents Reaction Rate = k [Haloalkane]
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E2 | Polar Protic Solvents favor E2 over SN2. STRONG Base Favors E2 because: base can deprotonate to free a pair of electrons. Reaction Rate = k [Haloalkane] [Base] Antiperiplanar proton
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Reminder: "Protic = Pi = double bonds use a Pi bond" | ||||||||||||||||||
Sn1-Sn2-E1-E2 |
Reaction Rate Substrate Stability of Intermediate Strength of Nucleophile Stereochemistry Solvent Rearrangements |
http://www.sparknotes.com/chemistry/organic4/sn1e1/section1.rhtml | ||||||||||||||||||
Markovnikov | more stable carbocation is formed. H and CH3- migration | |||||||||||||||||||
antiMarkovnikov | less substituted alkyl bromide bond is formed. | HBr/hv with Peroxides | ||||||||||||||||||
Hoffman Rule | ||||||||||||||||||||
Zaitzeff Rule | priority | |||||||||||||||||||
Molecular Geometry | ||||||||||||||||||||
Trigonal Bipyramidal | ||||||||||||||||||||
Organic Acids Acidity |
Henderson Hasselbach pH = pKa + log [A-]/[HA] low pKa = High Ka = Strong Acid. If pH < pKa: Protonated. If pH > pKa: BASIC, Unprotonated |
A proton becomes acid when the bond breaks heterolytically. Homolytic Bond Breaking: Homolysis: the bond breaking kcal/mol is higher = requires more energy. Electron pairing in heterolysis stabilizes. |
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Alkene Reactions | ||||||||||||||||||||
Alkene HaloAlkane Addition | Markovnikov, Not Enantioselective. | |||||||||||||||||||
Alkene HaloAlkane Addition with Peroxide | Gives Halogenated less substituted haloalkane. Antimarkovnikov. |
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Alkene Hydration Acid Catalyzed | Gives Alcohol Pi bond is protonated initially, forming a carbocation. |
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Alkene Oxymercuration/Demercuration | Gives Alcohol. Markovnikov. Pi bond is protonated initially, forming a carbocation. |
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Alkene Hydroboration | Give Alcohol Antimarkovnikov. |
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Alkene DiHalogen X-X Attack | Sn2: Trans Product Reaction proceeds by instant (-) polarization of 𝛑 bond by X-X Reaction can yield Halogenated and -OH groups. -OH is Markovnikov. |
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Alkene Epoxide Formation | Gives Epoxide and Carboxylic acid. Followed by acid or base hydrolysis to give Diol. |
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Alkene Oxidation with KMnO4 | Gives cis-Diol trans diol with peroxy acid. |
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Alkene Hydration (Reduction) (cis or trans) | Gives Alkane. H2 with Ni, Pd, Pt. cis addition. Lindlar Catalyst with dopant stops reaction at alkene. trans addition is with Na, NH3 |
Recall Reduction. | ||||||||||||||||||
Alkene Ozonolysis | Gives Ketones. Reactant O3 + Zn in H20 |
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Aromatic Compounds | Aromaticity: Huckel Number: 4n + 2; Cyclic, free p orbital with a Huckel number, flat and planar. Can be accomplished via Cyclic Delocalization , Resonance, Conjugation If an electron like Oxygen is in the bond we only use one pair of electrons for aromaticity Examples: Purine, Pyridine, Thymine |
Good Reference: https://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/benzrx1.htm | ||||||||||||||||||
Aromatic Electrophilic Substitution | The Benzene ring is succeptible to electrophilic attack. Heat is required because the ring is 𝛑 stabilized. Ortho/Para: have lone pair of electrons on the atom bonding the ring. with the exception of alkyl R. -NO2 is a META deactivator
Activators have free electrons in the atom bonded to the benzene ring: -NH2, -OC6H5, -OR, -O(-) OrthoPara Deactivators: Cl, Br, I are deactivators |
Deactivators increase anion stability upon protonation: acidity is increased. | ||||||||||||||||||
Aromatic Diels Alder | Concerted Formation of Cyclic Compounds from conjugated diene. Dienophyle = alkene or alkyne Diastereoselective |
Reference: http://www.organic-chemistry.org/namedreactions/diels-alder-reaction.shtm |
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Ketone Reactions | Keto/Enol Tautomerism Acid Alpha proton Ketones do not undergo substitution reactions. Beta keto Acid. Beta keto ester. |
Ketone Formation from Secondary Alcohols with Chromate Oxidation. | ||||||||||||||||||
Ketones: Acetal | Cyclic Contains 2 ketones Biologicaly Important. |
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Ketones: Hemiacetal | Cyclic Contains 1 ketone Biologicaly Important |
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Ketones: Imines | Convert the Carbonyl to an Imine | |||||||||||||||||||
Ketones: Aldol Condensation | "one ketone bond is conserved and bonds with a double bond through the alpha carbon, after dehydration, so the carbonyl oxygen of the ketone that does not have alpha hydrogen is lost. study mechanism
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Acyl Group | Carboxylic Acids> Acyl Halide, Acid Anhydride, Ester, Amide | Acyl derivatives interconvert to lower reactivity. Acid Halide > Acid Anhydride > Ester > Amide less hindered carbonyl is more reactive. |
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Carboxylic Acids | Acetate CH3 COOR Acidity Order: HC l> Carboxylic Acid > Substituted Phenol > diketone > ketone |
Bases Deprotonate to give COO- Salts | ||||||||||||||||||
Carboxylic Acids: Nucleophilic Addition Elimination |
electronegative groups allow attack at the Carbonyl and serve as good leaving groups. | |||||||||||||||||||
Carboxylic Acids | Transesterification: Alcohol + Carboxylic Acid gives Ester. | |||||||||||||||||||
Ester | are neutral in solution. | |||||||||||||||||||
Ester Hydrolysis | Nucleophilic Acyl substitution : Addition Elimination : Saponification Acid and Basis Catalyzed |
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Inorganic Esters | Central Carbon P, S. Contain more than one double bond. | See reaction of PBr3 with 3ROH -> H3PO3 + 3RBr | ||||||||||||||||||
Amines | Reductive Amination: Amines Attack of Ketones to yield 1,2,3ry substituted Imines that are Reduced with H2/Pd to Amines. Amines to Alkenes via HoffMann Elimination: Less substituted alkenes. |
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Amides | Acid Base Reactions with Carboxylic Acids Basic Leaving groups decrease reactivity of Acid Chlorides with respect to Anhydrides> Esters>Amides Hoffman Rearrangement: Amides are converted to Amines |
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Imines | Schiff Base R1R2C=NR3 | |||||||||||||||||||
BIOCHEMICAL | Sugars, Proteins, Fats, Metabolism, pKa, Anomeric Carbon See SSSFFF Biology |
Good References: http://www.chem.ucla.edu/harding/IGOC/IGOC.html |
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SUGARS | Fructose, Glucose, Ribose LOOK at chirality FARTHEST from C1 to determine L/R. Sucrose: Glc + Fru: Alpha-1,2 Lactose: Gal + Glc: Beta-1,4 Maltose: Glc + Glc: Alpha-1,4 Cellobiose: Glc + Glc: Beta-1,4 Glycogen: α 1-4 |
EPIMERS are NEVER Enantiomers. Epimers differ only in one stereogenic center that IS NOT the last chiral carbon. Alpha/Beta epimers: Alpha = Axial, Beta = Equatorial HAWORTH Projection: Beta is UP!!! |
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Monosaccharides Sugars |
D, L Aldohexose vs ketopentose, vs aldotriose (threeOHgroups) ketohexoses (6OH and 1 C=O) Anomeric Carbon: cyclic: opposite the CH2OH outside the rinh C1 orientation |
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Hexoses | Glucose | |||||||||||||||||||
Pentoses | Xylose Ribose |
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Sulfur Containing Molecules | Mesylate, Triflate, Tosylate | |||||||||||||||||||
AMINO ACIDS | All natural Amino Acids are L, amphoteric Carboxylic pKa aprox 2. Amino Group pKa aprox 10 |
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Extraction | Form salt to become water soluble: Carboxilic acids are extracted with weak bases. NaHCO3 is better than NaOH because it destabilized aromatic structures.
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10 Enzymes Everyone should know | Glycogen Phosphorylase Phosphoglucomutase Glucose 6-Phosphatase ATPase Hexokinase / Hexose / Dehydrogenase / Oxidase Amylase Galactosydase CYP450 Cytochrome Oxidase
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Reactant List | HNO3 | EAS Activator | ||||||||||||||||||
Br2 + FeBr3 (heat) | EAS Bromination | |||||||||||||||||||
H2SO4 (heat) | EAS Sulfonation | |||||||||||||||||||
Friedel-Craft RCOCl + AlCl3 (heat) | EAS Aryl Ketone | |||||||||||||||||||
Friedel-Craft RCl + AlCl3 (heat) | EAS Alkylation | |||||||||||||||||||
Hg(OAc) in Water then NaBH4 | Alkene Oxidation to Markovnikov Alcohol | |||||||||||||||||||
BH3 in THF then H2O2 | Alkene Anti Markovnikov Alcohol | |||||||||||||||||||
KMnO4 | cis Diol | |||||||||||||||||||
OsO4 | cis Diol | |||||||||||||||||||
PCC | Anhydrous Oxidant: 1ry Alcohol to Aldehydes | |||||||||||||||||||
CrO3/ H2CrO4/Cr2O7-2/CrO3 | Aqueous Oxidants: 2ry Alcohol to Ketones | |||||||||||||||||||
NaBH4 in EtOH |
Reductor of Carbonyl | |||||||||||||||||||
LiAlH4 in Ether (aprotic) | Reductor of Carbonyl | |||||||||||||||||||
NaH, KH | Hydride bases | |||||||||||||||||||
Grignard RMgBr in Acid | Reductor of Carbonyl + R | |||||||||||||||||||
RLi | Reductor of Carbonyl + R | |||||||||||||||||||
Wittig Phosphonium Ylide | Reductor of Carbonyl to Alkene | |||||||||||||||||||
NaOH/H2O Acid | Aldol Condensation. Base attacks Alpha proton. Beta Hydroxyl Carbonyl or Alpha/Beta unsaturated Carbonyl |
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NaOH / KOH | Saponification | |||||||||||||||||||
SOCl2 | Inorganic Ester reactions. | |||||||||||||||||||
PBr3 | ||||||||||||||||||||
NaHCO3 | Extraction of Carboxilic Acids | |||||||||||||||||||
10% HCl | Extraction of Amines | |||||||||||||||||||
Tosyl Chloride | Stabilizez anion charge in COO-, H leaves | |||||||||||||||||||
Michael | ||||||||||||||||||||
Wolf-Kishner Reduction | ||||||||||||||||||||
Molecules to know | Furan, Pyran, Toluene, Naphtalene, Phenanthrene | |||||||||||||||||||
Polymer Chemistry | ||||||||||||||||||||
Elastic Properties | Elastic Limit | |||||||||||||||||||
Thermal Expansion Coefficient | ||||||||||||||||||||
Shear | ||||||||||||||||||||
Compression | ||||||||||||||||||||
SEPARATION TECHNIQUES |
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DISTILLATION | ||||||||||||||||||||
SHORT PATH DISTILLATION | ||||||||||||||||||||
FRACTIONATED DISTILLATION | ||||||||||||||||||||
SUPERCRITICAL FLUID EXTRACTION | ||||||||||||||||||||
DERIVATIZATION | ||||||||||||||||||||
CHROMATOGRAPHY | ||||||||||||||||||||
DETECTION TECHNIQUES |
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Detection Techniques | Detection IR | |||||||||||||||||||
IR cm^-1 |
3600-3200 -OH 3300 Amines (OH broadest, NH sharper) 3000 C-H 2300 - 2100 C---C or C---N 1700 C=0 (Carbonyl, Carboxylic Acids) 1650 C=C |
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CHROMATOGRAPHY |
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Chromatography | Separation of derivatized diastereomers. Enantiomers can be reacted with a known stereochemistry comp. | |||||||||||||||||||
GAS Chromatography |
FID TCD ECD NPD |
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Wet Column Chromatography |
Also referred to as Gravity Column Chromatography https://www.youtube.com/watch?v=HGGT5Mo-wPI |
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Planar Chromatography |
TLC R factor: Polar molecules are retained by Silica, so have smaller R f. | |||||||||||||||||||
Size Exclusion Chromatography SEC | Large Elute First. |
Size Exclusion, gel permeation chromatography or gel filtration chromatography. separates particles on the basis of molecular size (actually by a particle's Stokes radius). It is generally a low resolution chromatography and thus it is often reserved for the final, polishing step of the purification. It is also useful for determining the tertiary structure and quaternary structure of purified proteins. SEC is used primarily for the analysis of large molecules such as proteins or polymers. SEC works by trapping these smaller molecules in the pores of a particle. The larger molecules simply pass by the pores as they are too large to enter the pores. |
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SDS-PAge |
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Scintillation counting |
Iodomelatonin in the presence of selective antagonist for the receptor We have pharmacologically characterized recombinant human mt1 and MT2 receptors, stably expressed in Chinese hamster ovary cells (CHO-mt1 and CHO-MT2), by measurement of [3H]-melatonin binding and forskolin-stimulated cyclic AMP (cAMP) production. [3H]-melatonin bound to mt1 and MT2 receptors with pKD values of 9.89 and 9.56 and Bmax values of 1.20 and 0.82pmolmg−1 protein, respectively. Whilst most Whilst most melatonin receptor agonists had similar affinities for mt1 and MT2 receptors, a number of putative antagonists had substantially higher affinities for MT2 receptors, inclu ding luzindole (11 fold), GR128107 (23 fold) and 4-P-PDOT (61 fold). In both CHO-mt1 and CHO-MT2 cells, melatonin inhibited forskolin-stimulated accumulation of cyclic AMP in a concentration-dependent manner (pIC50 9.53 and 9.74, respectively) causing 83 and 64% inhibition of cyclic AMP production at 100nM, respectively. The potencies of a range of melatonin receptor agonists were determined. At MT2 receptors, melatonin, 2-iodomelatonin and 6-chloromelatonin were essentially equipotent, whilst at the mt1 receptor these agonists gave the rank order of potency of 2-iodomelatonin>melatonin>6-chloromelatonin. In both CHO-mt1 and CHO-MT2 cells, melatonin-induced inhibition of forskolin-stimulated cyclic AMP production was antagonized in a concentration-dependent manner by the melatonin receptor antagonist luzindole, with pA2 values of 5.75 and 7.64, respectively. Melatonin-mediated responses were abolished by pre-treatment of cells with pertussis toxin, consistent with activation of Gi/Go G-proteins. |
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SPECTROSCOPY |
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Mass Spectroscopy | Base Peak is the largest peak. It is fragmented. Parent peak is the ion of the molecule without fragmentation. Uncharged molecules are not detected. More fragmentation produces smaller peaks. Quantitative and Qualitative: The m/z ratio |
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Nuclear Magnetic Resonance | Shielding/Deshielding Electron donating are shielding, Electron Withdrawing are deshielding. Left axis has larger number. So deshielded protons appear to the left=downfield (-RCOOH). Shielded protons appear to the right (H-C-CH3x3) 1-propyne vs 1 propene: s haracter is less shielding. ORDER: Aldehyde and Carboxylic- Aromatic- Vinillyc--- Halogen, ether, allyl, alkyne, benzyllic . |
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H NMR | Allylic proton is very deshielded. Memorize the 6-8ppm region is Aromatic. Geminal Methyl Groups are identical. |
Good Reference: http://www.stolaf.edu/depts/chemistry/courses/toolkits/380/js/nmr1/ |
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C NMR | Height of Peak proportional to number of H attached to C. | |||||||||||||||||||
BIOCHEMICAL TECHNIQUES |
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BIOCHEMICAL TECHNIQUES | BIOCHEMICAL TECHNIQUES | BIOCHEMICAL TECHNIQUES | ||||||||||||||||||
ELISA | Enzyme Linked Immuno Sorbent Assay Antibody binds antigen-Wash-Enzume Linked antibody-Wash-Color Change |
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VULCANIC CHEMISTRY | BIOCHEMICAL TECHNIQUES | |||||||||||||||||||
Vulcanic Chemistry
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Tectonic Plates Nazca Plates Subduction Hotspots, Magma, 700C to 1600C, SiO2, Fe, Mg, 2200-2800kg/m3, IDDP magma geothermal energy generator Phreatic vs Phreatomagmatic vs Magmatic Eruption Magmatic Eruption: Decompression of Gas Phreatic Eruption: Superheated Water Expansion Phreatomagmatic Eruption: Compression of Gas within Magma Hawaiian<Strombolian<Pelean<Plinian<UltraPlinian Mount Pele in St Pierre, Martinique exploded in 1903 killing 30k. |
Tools for Earthquake Prediction: Thermal tools: Heat Chemical: Vulcanic Chemistry, Water Quality and Gas Composition Nuclear: Particle Counters through volcanic Mass Mechanical: Earthquakes and Sound waves. |
H | He | ||||||||||||||
Li | Be | B | C | N | O | F | Ne | ||||||||
Na | Mg | Al | Si | P | S | Cl | Ar | ||||||||
K | Ca | Ga | Ge | As | Se | Br | Kr | ||||||||
Rb | Sr | In | Sn | Sb | Te | I | Ke | ||||||||
Cs | Ba | Tl | Pb | Bi | Po | At | Rn | ||||||||
Fr | Ra | ||||||||||||||
One Arcminute is equal to 1/60 of one degree. One Arcsecond is equal to 1/60 Arcminute. So One Arcsecond is equal to 1/3600 of a degree. | ||
One degree is 1/360 of a circle. One Arcminute is (1/60)(1/360)=(1/21600) of a Circle. 1deg=3600arcseconds; | ||
To complete a circle of 360deg, with a frequency of 500arcsec/century will take (360)(3600)/500 centuries. | ||
CHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEM CHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEM CHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEM CHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEM CHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEMCHEM ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ ENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERING ENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERING ENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERING ENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERING ENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERINGENGINEERING
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The Engineering World
PROJECT MANAGEMENT
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Value ManagementPredictive Study Project Planning Risk Management Design Management Information Management Supply Chain Management Procurement Commissioning |
Engineering Finances
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Benefit Analysis
Sources of Finance Equity, Loans, Working Capital Microsoft Project |
Tank Inspections (Pharmaceutical)Storage Tanks BioReactors Portable Tanks |
49CFR180.407 Electropolishing and Surface Priming Impeller Selection, Mixing Profiles, Heat Profiles Turnover Packages Inspections, Materials Selection, Pipeline Installations, Leak Tests, Seals and Gaskets Cleaning Skits, Soap Selection, Cleaning Strategies, Cleaning Validation |
Laboratory Inspections
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Quality Laboratory Inspections Non Conformance Investigations LIR's Product Performance Product Release Material Inspections CAPAs and EVs |
Lyophilization |
21CFR is FDA Pressure Stage vs Temperature Stage High Vacuum, ISO5 to ISO8 Facility Particle Counters Viable and Non Viable Point Differential Finite Element Analysis CFD |
Cell Culture (Biotechnology)
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21CFR610 General Biological Products Cell Growth and Scale Up: From Clones to Grafts. Cell Culturing and Lab Analysis: PCR, North to West Blots. Electrophoresis, Gene Chips, Sequencing Analysis. Biotechnological Testing Equipment Comissioning. Centrifuges, Filters, Pumps, Dispensing Systems. Test Selection and Design of Experiments. |
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Water Treatment Inspections |
40 CFR414 Effluent Guidelines OCPSF Organic, Chemical, Plastics, Synthetic Fibers Waste Water Pretreatment Release Permitting |
DOCUMENTATION CONTROL
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Document Qualification User Requirements GMP/ISO Specifications URS, IQ, OQ, PQ
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HVAC System Validation
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Installing Compressed Air Lines Installing Chillers Installing Refrigeration Units Installing Boilers
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Flammable Hot Work |
Working with Flammables Fire Safety and Regulations NFPA Storage and Safety Explosion Prevention Fire Management |
Computer System Validation CSV
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Energy Savings
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Illumination LED Systems Control Panels Power Consuption Estimation
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Packaging
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Quality |
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Drug Delivery Systems
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Controlled Release Systems Compounding Strategies Solid Blending Solutions, Emulsions, Suspensions. Drug Delivery Technologies |
Synthetic Materials |
Compounds Semiconductors / Superconductors Organic / Inorganic Polymers |
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ENGINEERING TRENDS:
INSTALLATIONS
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Heat Exchangers, Chillers, Air Handling Units, Compressors, Pump, Ducts, Piping, Refrigerant
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IQ - OQ - PQ
Wrap UpAir Filter References
GMP References
Design References
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HVAC system concepts
HVAC system-critical parameters
Cleanroom air classifications and explain how they are applied
Role of HVAC in protecting products
Examine typical HVAC system designs utilized for bulk, oral solid dosage, sterile, biopharmaceutical, and packaging and warehousing operations
Understand the basics of process laboratory HVAC
HEPA filter theory, application, monitoring, testing, and repair
HVAC maintenance requirements
ENGINEERING TRENDS: CLEAN ROOM TESTING:
CLEAN ROOM TESTING
Tests | Description |
Airflow Volume / Velocity Readings | Assures that both unidirectional and non-unidirectional flow areas are properly balanced and unidirectional zones are maintaining proper air patterns |
Room Air Exchange Rates | States if the area is meeting its design airflow |
HEPA Filter Integrity Testing | Tests HEPA filters and system for leaks |
Non-viable Particle Counting | Reports the amount of airborne particulate of a specified size in the clean zone |
Temperature / Relative Humidity Testing | Examines whether the air HVAC controls are functioning properly and uniformly |
Pressure Cascade Monitoring | Verifies that room differential pressures are operating according to design |
Air balancing | Adjusts airflow in the air handling systems to achieve design airflow, room air exchange rates, and pressure cascade |
Airflow Visualization Testing | Qualitatively verifies airflow direction using a source of visible fog |
Viable Environmental Monitoring | Samples both the air and surface for microbe enumeration and identification |
Compressed Gas Testing | Assures that the compressed gas sources meet the requirements of the controlled environment for contamination and microorganisms |
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References: [cGMP], Institute of Environmental Sciences Technologies [IEST], and International Organization for Standardization [ISO].
WATER MANAGEMENT
Waste Water Systems
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UNDER CONSTRUCTION
WATER MANAGEMENT SYSTEMS
Typical Water Management Systems used by manufacturing and power plants include the following processes:
Desalinization
Filtration
Softening
Disinfection
Sanitization
Iron Removal
Precipitation
Reduction of Inorganic and Organic Material
ENGINEERING TRENDS: ENGINEERING BOTTLENECKS
Are you managing an unmaneagable process? What are the bottlenecks? Personnel, Systems, Budget, Seasonal Variations, Publicity, Vendors?
Personnel Bottlenecks: Rotten Apples: One employee...
Project Management (PM) does not deal with "Business as Usual", PM deals with projects or with tasks that have a beginning, middle and end, and evolve over the course of time until the project is handed over to a client.
PMN balance Budget, Time, and Money and Staff in the phases of Planning/Initation, overseeing Execution and Monitoring, Troubleshooting and Closing.
PMN execute in different ways under Information Technology, Biotech, or Construction. Generally PMN deal with Scheduling, Tracking, Budget Control, Risk Management, Strategizing, Quality Management, Workflow Control, involving Resource Allocation, Human Resource Management, Material Resource Management, and Time Management.
Identify Deliverables: Benchmarks
Draft Project Plan:
Draft Project Checklists: Outline all Tasks needed to complete the project and check tasts as they are completed.
Update Stakeholders with Presentations
Value Management
This post is about learning the basic fundaments about calculating Value, reducing losses, and understanding the constraints related to project management. The list will not be exhaustive, however, with your help this list can be refined and sharpened to focus on the more salient or pertinent calculations regarding this matter.
Most projects can be managed with tracking sheets but Engineering Projects involve short term and long term Predictions on the impact of expenditures on the overall budget and these considerations that employ predictive tools for forecasting and planning. These calculations have imminent effects on the final physical structure and often lead to drastic project overhaul or expansions.
It is why computational power
Planned value (PV):The approved budget for the work scheduled to be completed by a specified date; also referred to as thebudgeted cost of work scheduled(BCWS). The total PV of a task is equal to the task’s budget at completion(BAC)— the total amount budgeted for the task.
Earned value (EV):The approved budget for the work actually completed by the specified date; also referred to as thebudgeted cost of work performed(BCWP).
Actual cost (AC):The costs actually incurred for the work completed by the specified date; also referred to as the actual cost of work performed(ACWP).
Schedule variance (SV):The difference between the amounts budgeted for the work you actually did and for the work you planned to do. The SV shows whether and by how much your work is ahead of or behind your approved schedule.Cost variance (CV):The difference between the amount budgeted and the amount actually spent for the work performed. The CV shows whether and by how much you’re under or over your approved budget.
Schedule performance index (SPI):The ratio of the approved budget for the work performed to the approved budget for the work planned. The SPI reflects the relative amount the project is ahead of or behind schedule, sometimes referred to as the project schedule efficiency.You can use the SPI to date to project the schedule performance for the remainder of the task.
Cost performance index (CPI):The ratio of the approved budget for work performed to what you actually spent for the work. The CPI reflects the relative value of work done compared to the amount paid for it, sometimes referred to as the projects cost efficiency. You can use the CPI to date to project the cost performance for the remainder of the task.
Schedule and cost variances and performance indicators are defined mathematically as follows:
Schedule variance (SV) = Earned value (EV) – Planned value (PV)
Cost variance (CV) = Earned value (EV) – Actual cost (AC)
Schedule performance index (SPI) = Earned value (EV) / Planned value (PV)
Cost performance index (CPI) = Earned value (EV) / Actual cost (AC)The final step when assessing task performance to date is to update what you expect your total expenditures will be upon task completion. Specifically, you want to determine the following:
Estimate at completion (EAC): Your estimate today of the total cost of the task
Estimate to complete (ETC):Your estimate of the amount of funds required to complete all work still remaining to be done on the task
PM: ISO3100 RISK MANAGEMENT Risks are about events that, when triggered, cause problems or benefits. Any event that may endanger achieving an objective partly or completely is identified as risk.
Identification: Once risks have been identified, they must then be assessed as to their potential severity of impact (generally a negative impact, such as damage or loss) and to the probability of occurrence.
Assessment: Once risks have assessed, all techniques to manage the risk fall into one or more of these four major categories:
Implementation and Review: Evaluate whether the previously selected security controls are still applicable and effective
Prioritizing therisk management processestoo highly could keep an organization from ever completing a project or even getting started.
Risk Analysis Tools:
Fault tree analysis (FTA)
Failure Mode and Effects Analysis (FMEA)
Hazard and operability study (HAZOP)
Risk traceability analysis
Tracking Tables
Identify (Source Risk) | Analyze | Response | Control (Monitoring | |||||
ID | Description | Category | Probability | Impact | Added Days | Status of Response | Response Cost | Total Cost |
x | Chiller Efficiency Drop | Utilities | 0.01 | High | 4 | Chiller Maintenance Pending | $x,xxx.xx USD | $x,xxx.xx USD |
Methodologies and Project Life Cycles 1
Project Management Certifications
Do you really need MS Project?
PROJECT MANAGEMENT TRENDS: STAFFING
Do you really need MS Project?
ENGINEERING TRENDS: QUALITY MANAGEMENT SYSTEMS: Trends in Administrations systems, philosophical differences between QMS, Hierarchical and Organizational Differences.
Drug Manufacturing Quality Documentation: Managing a Drug Manufacturing Site requires precise control over all steps that impact the Identity, Purity, Efficacy, and Quality of the product. The high level of precision requires that manufacturing tasks are well understood by personnel and these tasks are not limited to steps making the drug product. Control requires ALL areas to provide the highest standards of as required by local and international standardizing and regulatory bodies.
Have you covered all aspects of the working site? Are you missing an area? Would you imagine working in areas where tasks were not defined? Documentation needs to describe the areas, processes, machines, units as well as steps, calculations and precautions.
There are many more areas that require precise documentation to provide the rigor and control required to produce a high quality chemical product.
In order to produce and control such documents facilities have document management systems that provide easy access to employees. Employees become familiar with the tasks before executing them and with these documents employees are Trained-and-Tested to provide a level of proficiency prior to execution. These documents are "Living Documents", what this means is that once drafted the documents are not destroyed. Instead they go through a lifetime of changes and these changes however minor are docmented and tracked within the document so people reading the document can see the changes to the document through revisions.
Changes do not become effective until 75-85% of all employees have been trained on the changes. So after rigorous control it is expeced that changes howere impactful or minor are taken into account by all employees driving continuous improvement.
PROCESS TRENDS: SERIALIZATION, GLOBAL HARMONIZATION: Packaging, Stacking, Monitoring, Storage, Shipment and Control.
New Medical Products
What considerations are needed to Manufacture a New Product
New Drug Application
New Dietary Supplements
New Biomedical Devices
New Drug Application
Investigational New Drug
Investigational IND includes:
Animal study data and toxicity (side effects that cause great harm) data
Manufacturing information
Clinical protocols (study plans) for studies to be conducted
Data from any prior human research
Information about the investigator
Permissions to transport drugs across state boundaries.
Drug Patent
Laboratory Data, Patient Data
Clinical Trials 21CFR312
CLINICAL TRIALS PHASE OVERVIEW | ||
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Drugs | Medical Devices | |
Phase 1 | Tested on Healthy Patients Maximum Tolerated Dose. Safety, Dose threshold, Biological Therapeutic Effect Size of Population <100
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Phase 2 | Tested on Patients with the Condition Side Effects
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Phase 3 | Tested on General Population Volunteers 100-1000 Patients Comparing Placebo and Current Therapies to New Therapy |
Evidence
New Dietary Supplements
New Biomedical Devices
Therapeutic Biologic Application (BLA)
Approval
International Medical regulations
EDQM European Directorate for the Quality of Medicines and Healthcare
Storage and Handling of Chemicals
Maximum Allowable Quantities
International Fire Code
Ladder Supports and Clearances
Voltage Requirements and Related Ground Faulting
Laminar Flow Hood Qualification
Clean Room Qualification
FIRE MANAGEMENT SYSTEMS
Fire Management Consulting: Prevention, Planning, Rescue Operations, Hazard Identification, Communication Protocols, Adherence and Enforcement of Policy are all elements of Fire Management
Goals(General): Prevent Injury, Preventl loss of Life, Prevent loss of Property
Objective (Metrics): Prevent ocurrence of fire and explosion (#). Provide Means of Escape (t). Contain, Control and Suppress fire and explosion origins. Decrease total number of work related casualties (h). Decrease total number of loss work hours. Decrease total number of work related injuries. Increase the level of safety by introducing added meeasures of protection in each task performed.
Fire Prevention Plans must be kept in writing and must be communicated orally to all personnel.
Establish a Storage and Handling Zone. Isolate zone from heat sources at least 35ft away. Consider mass transfer of vapors. Consider also temperature effects that may volatilize liquids far away from a heat source.
Isolate the Handling Zone from electric conduction by grounding the casing.
In the Event of a fire Understand the Elements of the Fire Triangle and how to isolate the heat source from the oxidant, or how to lower the temperature of the fire.
Know Fire Chemistry: Stoichiometry, LEL, UEL, LFL, UFL, Heat of Combustion, Latent Heat, Heat of Vaporization, Conduction, Convetion, Radiation, Reid Vapor Pressure, Ignition energy, Ignition Temperature, Heat Value, BLEVE, Vapor Cloud Explosion, Overpressure, Backdraft, Flashover, Flash Point,
Causes of Explosions: Spark, Arc, Heat Conduction, Convection, Radiation, Deflagration, Collision, Friction, Nature, Chemical Reaction, Nuclear Reaction
Two Types of Explosion: Deflagration vs Detonation
Effect of Pressure and Temperature on the LEL and UEL. The Flash Point is the lowest temperature and pressure at which a vapor/liquid may spark or ignite.
Explosions are divided into two different categories. Deflagration and Detonations, both invove equilibrium procesess of a gas, an oxidizer, and heat in a medium undergoing expansion. Deflagrations occur with mass transfer at low velocites directed at the reaction zone wheras Detonations are violent and the expansive gas is the reactive zone.
Design Considerations: Spacing, Protocols, Procedures, Sewage Control, Diking, Housekeeping, Tool Inspections, Heat source elimination, area desinations, Training.
Fire and Electricity: Eliminate Arc, or Sparks by using rated currents far from the boundary limits for conduction or arcing of current. Ground, and Bond equipment, tanks, storage bins, Understand Charge dissipation, Capacitance, Resistivity, Induction
Understand Fixed and Portable Fire Protection Systems (OSHA29CFR1910.160): Extinguishing Agent, Nozzle, Piping, Control Pane, Alarm, Detector, Visual and Audible Warnings. Semianual inspections, Desired extinguishing concentrations shall be dispensed under 30seconds.
Fire Extinguishers: Located every 75ftA/D fire, 50ftBfire, when close to a flammable liquid storage area. 1 Fire Extiguisher per 3000sqft of building area.
Fire Extinguishing Materials | ||
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Substance | Supresses | Capacity |
Water | A Fire | |
CO2 | B/C Fires: Oil Fires Gas Fires Electrical Fires |
22, 9, 7, 5, 3kg. |
FOAMs | ||
Ammonium Phosphate | ABC Fires | 10, 5, 1kg |
Sodium Chloride | C Fires | dry powder only |
Sodium Carbonate | C Fires | dry powder only |
PPE Capacities | ||
Fire Hose | 100gpm-1000gpm | |
Fire Truck | ||
Dry Chemical | Hydrostatic Test 6 years | |
Develop Cost Reduction Strategy
Develop Service Requirements:
Material Specifications for product, packaging, and labeling
Testing requirements
Budget
Quantities required
Shipping Timeframes
Vendor List: QA Screens Vendor List for Compliance issues from FDA, Recalls and Warning Letters. Operational Licenses, Certifications, Company Structure, Data Management and General Operational Qualit of the Vendor is Rated by QA.
Vendor Selection:
Involve a Cross Functional Team: R&D, Engineering, QA, Corporate. Material selection impacts directly product quality and company identity. All players should be involved in detecting vendor strengths and weaknesses.
Perform Facility Audit: Confirm strategic, logistic and productio infrastructure is present. Note any Structural issues that may affect product characteristics. Address long term manufacturing plan with site leaders to ensure no manufacturing changes will impact your supply.
Develop Quality Agreement:
Agree that changes in the manufacturing process or issues related to FDA inspections are reported and prevent their impact in your manufacturing process. Ensure that CAPAs, OOS, Customer Complaints are reported and addressed.
Monitor Qualification Status: Re-qualification process and on-site audit
PROCESS TRENDS:
CONTINUOUS IMPROVEMENT
FDA: http://www.accessdata.fda.gov/
Key words: Safety, Identity, Strength, Quality, Purity... Quality Control Unit...Batch Records Controls, Uniformity,Complaints, Surfaces not reactive, additive, absortive; Sanitization vs Sterilization; Justification of Deviations; Pyrogen, Containers, Second Person Verificatin, In-process testing; Bioburden, Time limitations, Reprocessing, 100% Visual/electronic Inspection. Tamper-Evident, Laboratory, Stability Testing, Release, Warehousing, Reserve Samples, Laboratory Animals, Records and Results. Are we now experts? Certainly not! Compliance is an ongoing Business, and Ongoing opportunity to correct everyday problems, new products require new solutions and as technology evolves, new facets require polishing by regulatory compliance. Quality is by Design!
The pointers are considered voluntary guidelines:
Definitions:
Identification of Critical Factors and Operational Ranges. The performance of the sterilization process is linked to the maintenance and control of a set of defined critical factors:Parameters to evaluate as critical factors may include, but are not limited to:
LogD vs T: da Z. para un log10 reduction de D
D(150C)=20min
F(12D)= Kill time 12 fold reduction of known
ENGINEERING TRENDS: MICRO STERILIZATION VALIDATION <USP>71
ETO STERILIZATION
https://www.youtube.com/watch?v=AO0VDRWUmvY
Use on: Metals, Ceramics, Polymers, Thermodegradable or Thermosusceptible materials.
GAMMA RAY STERILIZATION (ISO 11137)
SAL of 10^-6 | Probability of a viable micro-organism present on the device must be equal to or less than 1 in a million. One in a million (or less) devices are expected to remain contaminated after terminal sterilization. A sterility test on 10-100 samples isn’t even close to reliably measuring a failure rate of 1/1,000,000 devices. |
CFU | Unit of Viable bacterial or fungal cells reproducing by Binary Fission |
[kGy] | absorbed units / unit mass |
D10 [kGy] | 1 log reduction on viable count. 90% reduction of total count. |
Sample Item Portion | Proportion of Sample manipulable in a laboratory. |
Sterility Test | http://www.nutekcorp.com/PDFs/white_why_web.pdf |
VDMAX-15 VDMAX-25 |
selected sterilization doses of 25 kGy and 15 kGy. The method for 25 kGy is applicable to products having an average bioburden less than or equal to 1,000 CFUs (colony forming units) per device. The method for 15 kGy is applicable to products having an average bioburden less than or equal to 1.5 CFUs per device. VDmax Method: Justification for a sterilising dose of 25 kGy or 15 kGy Bellow is an example of the procedure for the VDmax 25 method on multiple production batches 1- Obtain product samples The product samples must be representative of routinely sterilised products. 2- Determine the average microbial load of 3 batches of 10 pieces 3- According to the table of ISO11137-2, determine the verification dose 4- Conduct verification dose experiments; irradiate 10 products at the verification dose and perform a sterility test on each of the products 5- Interpret the results: Accept the 25 kGy sterilisation dose if 0 or 1 of the 10 pieces is positive. Conduct verification dose confirmation experiments if 2 are positive. Do not accept the verification if there are more than 2 positives 40 products are required for this method. This method is only viable for validating sterilising doses of 15 or 25 kGy. |
Method 1 | 1- Select the sterility assurance level (SAL) and select 10 product samples from 3 independent production batches (or 30 samples) 2- Determine the average microbial load of the 3 batches of 10 items (method based on ISO 11737-1) 3- Obtain the verification dose (referring to table 5 of ISO11137-2) 4- Conduct verification dose experiments on 100 irradiated pieces (method based on ISO 11737- 2) 5- Interpret the results 6- Establish the sterilisation dose based on the results (maximum of 2 positives out of 100 pieces) 130 products are therefore required for this method. The advantage of this method is that it enables any sterilising dose to be validated. |
Method 2A Method 2B |
1- Select the sterility assurance level (SAL) and obtain samples of the product (at least 280 samples for 2 independent production batches) The product samples must be representative of the products routinely sterilised. 2- Conduct the incremental dose experiments; irradiate 20 pieces at incremental doses of 2 kGy beginning with the 2 kGy dose and using at least 9 values. This is to be done for each of the 3 batches involved. Perform a sterility test on each of the products. 3- Conduct verification dose experiments; irradiate 100 pieces at the verification dose and perform a sterility test on each of the products 4- Examine the results 5- Establish the sterilising dose based on the results |
Performance Qualification (PQ)
Product PQ: carried out under the supervision of the product manufacturer. This determines compliance of the sterilization process on the product.
1) Dose Mapping: The first step of the validation is to verify that every product in the sterilization container receives a dose complying with the specifications (for example 25-40 kGy). As the dose received by the products can depend of the density of the products and their position in the sterilization container, before performing the dose mapping validation, the product loaded patter shall be established. With this product loaded pattern, dosimeters will be placed to measure the dose received by the products at different points of the sterilization container.
2) Validation of the sterilising dose: This part of the product PQ makes it possible to validate the minimum irradiation dose required to sterilise the product (i.e. to guarantee a sterility assurance level (SAL) of 10-6). 3) Validation of the maximum dose: This part of the validation procedure verifies by means of various kinds of tests that product characteristics are not degraded by irradiation, even at the maximum dose.
PROCESS VS PRODUCT CONTROL:
Cp | (USL-LSL)/6σ (USL- Avg.)/3σ or (Avg. - LSL.)/3σ Engineering Tolerance / Natural Tolerance Processes in control are close to Cp = 2. This parameter tells you what is the "process spread" assuming that manufacturing is normal. Cp shows whether the distribution can potentially fit inside the specification A high Cp tells you that variation in output is low around process specification. Uses Subgroup Variation. |
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Cpk | Cpk = Min(CpU,CpL) Ability to produce outcome within specification Desribes how mean is centered within Specification. Shows whether the overall average is centrally located. Cpk=2 means your width can grow 2 times before going OOS Cpk can never exceed Cp. Cp can be seen as the potential Cpk if the overall average is centrally set. If Cp is 1.20 and Cpk is 0.69. This shows that the distribution can potentially fit within the specification. However, the overall average is currently off center. The Cpk value does not state whether the overall average is offset on the upper or lower side. Cpk=1.0), a process will produce approximately 99.73% good product or .27% bad product. At Cpk = 1.33.the process will manufacture approximately 99.9937% good product or .0063% bad product. |
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Pp | (USL-LSL)/6σ (Upper Spec - Lower Spec) / 6 sigma OR (USL- Avg.)/3σ or (Avg. - LSL.)/3σ Uses Overall Variation |
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Ppk: | Ppk = Min(PpU,PpL) Sshould be close to Cpk if process is stable and variation is small. Estimator of process control before process has been controlled, usually when process has output a low number of products Ppk is used to determine how "in control" a process is. |
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Accuracy | Accuracy = Xbar - X Residuals = Difference between observed and Estimated value |
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Precision |
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Nelson Rules | Special Variation Rules: Rule 1: 3std from mean Rule 2: 9 consecutive points above or below mean Rule 3: 6 or more points continually increasing or decreasing Rule 4: 14 or more points continually oscillating. Rule 5: 2 or more points are consecutively more than 2std from mean in linear of defined linear direction. Rule 6: 4 or more points are consecutively more than 1std from mean in linear or defined linear direction. Rule 7: 15 or more points are consecutively within 1std from mean. Rule 8: 8 points are out outside of 1 std deviation from mean in both directions. |
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Tolerance | Difference between the USL and LSL. | ||||||||||||||||||
Confidence Interval | "We are 95% confident that our interval will contain the sample mean of the population... that is to say that we are 95 times out of a 100 finding the mean of the population within our confidence interval and 5 times out of a 100 we are not. 95% speaks about the process of finding the confidence interval and has Nothing to do with the mean of the population" |
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Power of Test | 1-Beta Increase: Required Sample Size, n; Detectable Difference, between the mean under H0 and H1, µ0 − µ1 ; Level of significance, α; Decrease: Variability |
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Gauge R&R | Gauge R&R is a test of variance between the effect of The Part, The Operator and the System
Variation = Vpart + Vgauge(R&R) Crossed R&R: Xbar and R
resolution= Sigma/Mu
Nested R&R: 1op, similar.parts.(destructive) Gauge Run Chart by Operator Repeatable: Instrument COPQ: cost of poor quality. |
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Z score | Standardized value of how one score compares with Population in terms of Standard Deviations.A z-score equal to 1 represents an element that is 1 standard deviation greater than the mean. Z = (x - mu) / sigma 2/14/34/34/14/2 |
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Hypothesis Testing Null Hypothesis |
Statement of rejection adopted to commence a statistical analysis. Null hypotheses are not inferred directly.The Null hypothesis is rejected by testing the validity of the opposite statement.
http://support.minitab.com/en-us/minitab/17/topic-library/basic-statistics-and-graphs/hypothesis-tests/basics/type-i-and-type-ii-error/ |
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P Value | Smallp-value (typically ≤ 0.05) indicates STRONG evidence AGAINST the NULL hypothesis, so you reject the null hypothesis. Largep-value (> 0.05) indicates WEAK evidence AGAINST the NULL hypothesis, so you fail to reject the null hypothesis p-values very close to the cutoff (0.05) are considered to be marginal (could go either way). |
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Error Tipo 1 | False Positive: Incorrect Rejection of null hypothesis. The probability of making a type I error is α, which is the level of significance you set for your hypothesis test. An α of 0.05 indicates that you are willing to accept a 5% chance that you are wrong when you reject the null hypothesis. For a fixed sample size, the probability of making a Type II error is inversely related to the probability of making a Type I error. Thus, in order to achieve a desirable power for a fixed level of significance, the sample size will generally need to increase. EX.: Null: Two medications are Bioequivalent. A type I error occurs if the researcher rejects the null hypothesis and concludes that the two medications are different when, in fact, they are not. |
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Error Tipo 2 | False Negative: Failure of rejection of False Null Hypothesis. The probability of making a type II error is β, which depends on the power of the test. You can decrease your risk of committing a type II error by ensuring your test has enough power. You can do this by ensuring your sample size is large enough to detect a practical difference when one truly exists. EX.:Null Two medications are Bioequivalent. The researcher concludes that the medications are Bioequivalent when, in fact, they are different |
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Isolating Special Causes | Pareto Charts Ishiawa Diagrams SIPOC: Supplier Input Process Output Customers |
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Kaizen | Group Effort driven towards Continuous Improvement Plan-Do-Check-Act
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T Test | Hypothesis test comparing the Mean of a Population vs a Reference Mean Student's T test: small population, deviates from Normal Distribution, gives a Probability Density Function. 1 sample T-Test compares mean of a population to the reference standard when the standard deviation of the population is unknown. 2-sample T-Test compares means of two populations. T Paired: Compares two ligated observations. Ex.: Before and After weight loss. |
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T value | Measures Difference in terms of Standard Deviations. The greater T value (+/-) the greater evidence against (to reject) Null Hypothesis | ||||||||||||||||||
P value | Probabilty that the Two Sided T value is above and below the T value in a T distribution. When the Null hypothesis is true the T value falls in this probability region with. High P value = True Null. Low P value = Data does not contradict Null Hypothesis. P values are calculated on the assumption that the Null is true for the population and that the difference between populations is by random effects. |
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ANOVA | Analysis of Variance: Hypothesis test that allows the comparison of variation between groups. F-Statistic: Similar to T-Statistic from a T Test. |
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Normality Test | Skewness and Kurtosis should be close to 0 in a Normality Test. Shapiro Wilk Test with p < 0.05 |
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System Suitability | Test to ensure Systems, Analytes, Columns, Reagents and Operators are functioning properly prior to formal Analysis Execution. | ||||||||||||||||||
Limit of Linearity | See Test Method Validation | ||||||||||||||||||
Limit of Detection | See Test Method Validation | ||||||||||||||||||
Attribute Charts |
NP-Chart: for monitoring the number of times a condition occurs, relative to a constant sample size, when each sample can either have this condition, or not have this condition P-Chart: for monitoring the percent of samples having the condition, relative to either a fixed or varying sample size, when each sample can either have this condition, or not have this condition c-Chart: for monitoring the number of times a condition occurs, relative to a constant sample size, when each sample can have more than one instance of the condition. u-Chart: for monitoring the percent of samples having the condition, relative to either a fixed or varying sample size, when each sample can have more than one instance of the condition. |
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DOX | Design of Experiments |
HVAC
HVAC BasicsAir Filters
HVAC Controls
Air Balance
Cleanroom Basics
LAB HVAC
Boilers: Boiler Video
CLEAN ROOM TESTING
[cGMP], Institute of Environmental Sciences Technologies [IEST], and International Organization for Standardization [ISO].
Airflow volume / velocity readings - assures that both unidirectional and non-unidirectional flow areas are properly balanced and unidirectional zones are maintaining proper air patterns
Room air exchange rates - states if the area is meeting its design airflow
HEPA filter integrity testing - tests HEPA filters and system for leaks
Non-viable particle counting - reports the amount of airborne particulate of a specified size in the clean zone
Temperature / relative humidity testing - examines whether the air HVAC controls are functioning properly and uniformly
Pressure cascade monitoring - verifies that room differential pressures are operating according to design
Optional tests include:
Air balancing - adjusts airflow in the air handling systems to achieve design airflow, room air exchange rates, and pressure cascade
Airflow visualization testing – qualitatively verifies airflow direction using a source of visible fog
Viable environmental monitoring [EM] - samples both the air and surface for microbe enumeration and identification
Compressed gas testing [compressed dry air (CDA) testing] – assures that the compressed gas sources meet the requirements of the controlled environment for contamination and microorganisms
Lighting, vibration, and sound tests – assures worker comfort
All other special tests from the ISO/IEST guidelines
SIX SIGMA:Statistical Tools allow to predict future failures when past behavior is well understood. For this the variables affecting the process need to be well understood and well accounted. Enter Six Sigma
ENGINEERING TRENDS: STATISTICS ANALYSIS: All statistical analysis rest on IMPLEMENTATION. All numbers are followed by Human Decision Factors HDF and are Masked by interpretaion of the Statistics. Clear understanding of what the statistic represents and THE LIMITS of the refered to Statistical Analysis will incide in the Decision Making Process DMK. So at the the end of the Analytical process what you need to know is that you have successfully completed a DFSSQBDSASSCARQEQAIQOQFATHTetc... the point is to guide events to ZWR0 error. Statistics are extremely powerful.
Computational power presents the ability of modeling and making very accurate predictions in a variety of PROCESS or SYSTEM model analysis. Although advanced Mathematical Skills allow interpretation it is through experience of MODEL ADJUSTMENT that Statistical Analysis tour-de-forces into a Continous Monitoring Program.
Implementation of Continuous Monitoring Programs are the result of Human and Technological capabilities. Humans place the sensors and interpret data, technology gathers data and accelerates computational calculations. In the End, the role of the Quality Officer / sea un engineer, biologist, statistician, technician, operator / su rol es de 1-Ajustar el proceso para prevenir errores continuos. 2-Predecir modos de fallas para evitar tiempo perdido 3-Desarrollar estrategias que maximizen el uso de recursos 4-Ganar un entendimiento completo del proceso y sus variables para destinar recursos.
Ya entendido esto y habiendo ganado un tren de conocimiento en estadistica aparecen los verdaderos retos de considerar las variables y tomar decisiones que consumiran tiempo y costo. Enter Design of Experiments DOX. Leaders in process inovation understand that the allocation of funds destined to the execution of tasks along with the managerial accumen of project leaders is the half fraction of the process improvement process gains equation. The flow of information from decision to execution may cascade through usually 3 to 5 levels (Cascade Decision Loss). In each step of the two way communication ladder data is Lost, Misinterpreted, mistakenly calculated, held back by professional jealousy, held back by impunctuality or even top level project rearrangements. It is in this crucial step that most companies loose their capital. Swift decision execution forecast are backlogged by every single employees ability to carry the execution of the plan without interference from outside influence to the project. Error prediction is an applied science highly valuable and continually reevaluated. The responsibility of managers in adequately interpreting data is also key in maintaining a forward vision of process improvement. Process analysis may get recirculated in the plan-do-check-check-plan cycle without swift determination of task execution. Understanding the 4th dimension is key in making accurate and timely Value Added solutions to improve Company Performance in the era of the information tsunami.
Reconsidering the role of a leader in today's dynamic business models: Who leads a project? the CEO, the Manager, the Team Lead, the leading Tech, the rookie? In some business models the True Leader is the Rookie. The novice is outside the box, has no prejudice, has not formed clans within the company, has not offended the next door cubicle, and is looking to make an impression within the organization. More importantly than imagery, is the actual execution of the task and its measurable impact in daily, monthly and quarterly business goals. In a group of 4 there is a high probability that someone is prioritizing outside of the main focus and seeking to politicize a process advancement by acting in the last moment. Taking the baton from a relay team in the last meter to claim the goal retorts. This strategery is extremely common in the workplace because the work load is compressed. In compressed work loads there is no tracking of what each employee is executing and how the employee is prioritizing tasks, less time there is to rearrange priorities, so that each employee is 'free' to jump in the final phase of the project once someone else takes it from 1st gear to fourth. Sometimes the manager is aware of the individual and group contributions and eliminates the need for employees to make claims in the meeting spaces. Competition is key but the goal of any company is to align employees with the Common Goal. Microscopic gaining works to foment competition within a division but it may halter progress by creating internal division.
What are some other instances where a manager needs to eye internal conflict?
Normal Probability Plot: | Tests data for normality, skewness, abnormal distributions. See Histogram. |
Histogram | Graphical Representation of numerical data, like. a Bar chart relating the frequency of numerical values. It helps to visualize the type of distribution of the population, wether it is normal or skewed. |
Boxplot | Data is presented in Quartiles, Median, Maximum and Minimum values. |
X-Bar, R-Chart, vs Individual | X-Bar charts the process mean through time. R-Chart charts the process range though time. Range = Xmax - Xmin Always look at R-Chart first. If R-Chart is Out of Control then the X-Bar chart is meaningless. R-Chart Trends: Repeated Values, OOS points.
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T-test | Whether mean differs significantly. Relates T values to P values. |
Chi squared | Whether Categorical data from two data sets are related and if their differences are due to sampling methods or purely random effects. Chi square tests can only be used on actual numbers and not on percentages, proportions, means, etc. |
How is a Non Conformance generated? Again, a non conformance is Detected.
Is a Non Conformance a CAPA? What is a CAPA? No, NCs may trigger a CAPA but an NC in itself is the detection of deviation or error in expected product, packaging or delivery performance.
In the Industrial setting NCs are generated out of the high expentancy of delivering a high quality product. Any minor deviation in expected results is a Root Cause for an NC.
NCs are investigated under several possible root causes stemming from Machine Behavior, Environmental Triggers, or Human Behavior and as such root causes are established when the determining factors have been dully and fully investigated. Machine Behavior takes into account the Tolerance and the acceptable boundary performance of the unit under NC. When a machine breaches Upper or Lower boundaries of performace an NC is triggered. Yet it is possible by Statistical means to detect NCs prior to occurring, like predicting the future.
About Root Causes: Lets Establish Machine-Environment-Human as the three main Root causes. The cause-fault tree is then stemmed from Machine-Maintenance Schedule-Material Failure-Material Reaction-Unknown Material Reaction-Power Failure due to Machine action... then enter Environmental: Rain, Snow, Humidity, Lightning, Power Failure, and other unnatended keys to root an adverse action, then Human: Lack of Training, Lack of Attention, Excessive Overwork, Work Flow Interruptions, Social Interruptions, Error, or Slack. The classification of these Root Causes is set upon by Management in each Site. Managing these Root Causes is key in preventing future failures and understanding -in depth- the root cause is key in establishing the actions to prevent future occurrences. The balance of managing and correcting actions when Humans are involved is a delicate subject because most of the times the Root Cause contains several main root causes in conjunction that lead to the NC event recorded.
Denial, Commitment, Ethos, Diligence, Leadership, Accountability, Stewardship, Role Description, Task Load, Past Performance, Training Record, even Personal and Familial issues are brought into the balance equation to determine the root cause of an event. Recall that Process Failures are costly, sometimes very very costly, all the while there are internal competition within organizations that lead to push and pull responsability for the NC. These are very delicate issues and are at the core of what make up any major company, organization or work structure. It is why here at SSSFFF we are interested in learning your perspective in these details. How does Culture, Polical Stability, Economy, and Technology interplay. What are the best models of management and do they work in the corners of Earth? How can micromanagement and laxity coexist? Are there tools to measure this amalgam of Human-Machine-Environment issues or is it fundamentally decided by gut feelings or by numerical calculations? The answer is always yes. Write to us at info@syntheticforest.net for your perspective.
What are equations governing Tank Loading, what are the thermodynamic ambience of the Tank, what are the clearance and dikes of the walls, are there Firefighting Measures to support a spill. Take the Tianjin Explosion: likely caused by either an Error in Loading, or an Error in Ventilation. The magnitude of tank explosions or BLEVES, Boiling Liquid Expanding Vapor Explosion can be witnessed in Tianjin or simply YouTube BLEVE... Tank safety is very important.
BLEVE 1: Train Car Explosion. Funny how the narrator at 1:10 claims a record was established for a tank blown by a bleve. Not funny that perhaps firefighters died in that explosion. It is why most Plant fires are either immediately contained or let to consume the matter it combusts. Decomposition gases in fires are extremely toxic, many material classes are combusted so fighting the fire becomes a difficult task of both accessing the source to prevent additional combustion and in the selection of fire retardant or fire extinguishing material to add to the flames.
BLEVE 2: The Tianjin Explosion.
Here at SSSFFF we take matters into accountability for Tank installations. Is your tank for Biotech? Pharma? Cosmetics or Food? Petroleum or Fuels? Gases? There are many considerations into tank work. Take a Fermentor for example. A Fermentor runs a biological reaction that once started it will see its product completed in 30 days. Any basic tank profile or design failure will affect the outcome each and every time, and it could take years to discover that a tank design feature was the root cause of a drop in yield in a site. Take a food tank, is it leaking, is the heat vest broken, are the transfer lines clean? Where good care meets good quality, excelent products emerge. Let us take good of your tank.
Each Tank is birthed through a process involving welders, engineers and inspectors. First select the right material supplier and review the material requested once on-site. Double check to ensure quality, chemical caracteristics, surface polish, electrodeposited finish, etc, is it 3XX? You need to know. The tank will sleep in a bed of rock, or will it need a safety layer underneath to prevent leakage. Was a geologist contacted to study the soil? A stable base is key in ensuring tank safety and longevity. Will your tank arrive prefabricated or will a civil engineer construct the wall. This is called Bunding and Ring Wall Construction. It takes into account natural disaster factors such as storm winds, tornado force shear, earthquake recurrence, and lightning strikes, even tsunami recurrence. So all weld points, joints, bolts and connections need to pass inspection before the next stages. Non destructive Ultrasonic or X Ray tests may be performed to ensure right connections. The roof is lifted and bolted, so now fill it up! Water quality test, corrosion prevention, and stirring measures should follow in place.
Next up Piping: What are the inlet and outlet pipings into a tank? Ball Valves, Needle Valves, Butterfly Valves, Diaphragm Valves, Gaskets, Seals, Metals, and Ratings. Where does the piping run from. Are there any intersections that flow into or out from the tank. What are the friction losses and how to account them. What is the tank insulation and Piping insulation. You need to understand blueprints to understand the flow into a complex installation. Usually tank are grouped in buldings called tank farms. Many pipes will flow into and out from the tank farm so it is of utmost importance to properly trace flow and to note any changes from blueprint to physical reality. A single change can mean a drop in quality or a loss of millions due to pressure losses or material product contact with a misplaced flow regulation unit.
Are there any environmental factors affecting the Tank use or is the tank heat cooled or coil warmed? All tanks have temperature operating ranges that ensure the quality of the materials inside. Here at SSSSFFFF we care about ensuring your tank's alarms are in place and that each valve works where it is intended and as intended. So tanks are a bit civil, mechanical, chemical and electrical.
Are you installing a Tank? Inspecting a Tank? Let us know. Our Engineers will Reach your Tanks to meet your cost and production requirements.
IEEE, Statics and Dynamics, down to computer language... How to separate URS from CSV?
CSVCSVCSVCSV
Circuits: Parallel, Series, Capacitors, AC-DC Rectifiers, Diodes, Switches, EMF, Lenz Law.
Batteries: Lead Batteries, Anodes, Cathodes, Electrodepositon.
Motors, ICCE, Crank to Cam, Alternators, Starting Voltage / Running Voltage = 6
Electrical Safety: Color Codes, Leather and Rubber Gloves, The neutral-ground-hot wire, electric shock safety, contact resistance. Welding. Wiring Installations. Here is a good link to understand home lighting installations.
Electric Motors, Alternators, rheostats potentiometer, variable resistances. Brushes, Commutators, Impellers, Harmonic Oscillators...
The electric motor works this way: First we have to ensure we are dealing with an Electric Motor and not an Electric Generator. An electric motor converts electrical energy into mechanical energy.
The electric generator works this way: Dynamos, Alternators take Power to Induce an electric Current. Rotor-Stator-Armature. Dynamos convert Power into Direct Current. Alternators into Alternating Current.
Alternating Current: Lenz Law: when a coil cuts through magnetic field lines, that cut generates a current flow proportional to the angle it makes with the magnetic flow, with a max current flow at 0 degrees and 0 current at 90 degreens.
Direct Current: Commutator: Insulated Collar connected to a segment of the inducing coil. This produces pulsating half wave direct current.
See the video here.
Edison:Direct::Tesla:Alternating.
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Transformers V2/V1=N2/N1, The primary coil, the secondary. Inductance.
Rectifiers: like diodes. AC to DC one directional transmitters.
Resistance, Permittivity, Conduction and Radiative Flow.
Electrical Repairs and Inspections are performed only by qualified personnel
No electrical connections withing 50ft of flammable.
No Electric chord Interference with ladders.
Explosion Proof lighting.
Ground Fault Interrupter.
Proper circuit voltage and amperage.
Grounded Tools, Temporary Lighting, or Double Insulated Tools
A great wealth of knowledge is needed to completely evaluate these systems.
Routine Monitoring and Evaluation is required to sustain acceptable concentration levels of substances in water.
Change Control documentation is warranted for planning and execution of process changes.
Refer to 40CFR, and 21CFR for the latest USA Federal Regulation Standards. Standards are included within the FDA, EPA, CWA, WHO and other standardizing bodies.
Welding Inspections and Certifications.
Bonding Metals, Metallic Transmutations
Nuclear Reactions
What tools do you need?
The history of machines.... Initially there were tools................(Boston Pops...).....
Many years have passed since Humanity developed tools... takes a grasp and gasp at evolution..............
Complex Machines
Virtual Machines
Are you a Company that is selling a Machine? Get a spot here!
ENGINEERING TRENDS: MACHINES
Process Machines: Conveyors, Elevators, Mills, Cranes, Compressors, Precission Cutting,
..........................................................................................................................................................................................................
Simple Machines Complex Machines Virtual Machines:
Simple Machines are Archetypes of what Complex machines are made up off. Newtonian Mechanics govern the use of Simple Machines. Complex and Virtual Machines are out of the current scope.
Levers, Pulleys, Gears, Roller, Winch, Knife, Inclined Plane, what else?
Know your Lever: Effort Arm, Resitance Arm, Pivot. Types of Lever. Type 2 Levers MA>1, Type 3 Lever MA<1
Know your Gear: Gear Teeth, Gear Diameter
Winch: Compounded Roller
Knife and Inclined Plane: A knife is an inclined plane where the plane moves sliding the load over it. Does a knife cut an atom? NO! A knife cuts a macromolecular structure that is composed of atoms. Can you cut a macromolecular structure? yes.
Know a Pulley: Moveable Pulleys, Fixed Pulleys, Compounded Pulleys.
Mechanical Advantage = Effort/Load
UNDER CONSTRUCTION UNDER CONSTRUCTION UNDER CONSTRUCTION UNDER CONSTRUCTION UNDER CONSTRUCTION
Let's build Something Together!!!
MODULAR HOMES
GREEN ENERGY HOMES
GREENHOUSE
ROADS
BUILDING A MODULAR HOME
Step 1 Plan your list of expenditures and draw a schematic model of the finished home. Be as descriptive as possible.
Total Square footage of SiteTotal Square footage of House
Total Number of Rooms: X
Step #2 Start The Build
Who do I call first? the engineer, the architect, the state permitting... Can I prefabricate the interior with finishes to shorten lead time?
Can I prefabricate plumbing or do I have to wait until the modules are completed?
Step #3 Routine Inspections and Correcting Errors
Step #Z Detecting Defects and Adressing their Correction
Step #ZZ Finishing. Terminaciones.
Modular Home Links:
1 acre = 43560sq-ft = 4047sq-m
GREENHOUSE
Preserves Radiative Heat by trapping absorbed heat.
Increases, and sustaing Temperature
Protects from Weather, Insects and Pests
Isolates growth from other Plants
Soil and Nutrient Standardization
Get TESTS:
Ultrasonic Testing
Infrared Camera
Air Velocity
Gas Composition
Ash Resistivity
Particle Size Distribution
Flow Regime
Temperature Mapping
Computational Flow Dynamics
Finite Element Analysis
Kaye Validator
HPLC
Gas Chromatography
TLC
Nuclear Magnetic Resonance
Mass Spectrometry
TEST METHOD VALIDATION: Experiments rating Test Method Performance. Test Method Validation involves editing and executing protocols (the METHOD) to test the adequacy of a given analytical procedure (the TEST), and by analytical we mean any activity that is measuring an observable wether qualitatively (categorical) or quantitavely. Test Method Validation answers the following questions:
Can the measurement system adequately discriminate between different parts?
Is the measurement system stable over time? Is the gauge response linear?
Is the measurement system accurate throughout the range of parts?
Does a gauge require Recalibration?
Is there any difference in measurement methods, or operators measuring the one identical part?
Test Method Table | |
---|---|
Accuracy |
Closeness between the average of one or more test results and an accepted reference value. Involves selecting a Standard or Reference point if none is available. ICH: minimum of 9 determinations over a minimum of 3 concentration levels covering the specified range (for example, three concentrations with three replicates each). Accuracy should be reported as percent recovery by the assay of known added amount of analyte in the sample or as the difference between the mean and the accepted true value, together with the confidence intervals. |
Precision | the closeness of agreement among test results obtained under prescribed conditions. |
Repeatability | Operator. The ability of an operator to consistently repeat the measurement of the part, using the gage, under the conditions. Closeness of the agreement between the results of successive measurements of the part, carried out under the conditions of measurement (operator) The ICH requires repeatability to be tested from at least 6 replications measured at 100% of the test target concentration or from at least 9 replications covering the complete specified range. For example, the results can be obtained at three concentrations with three injections at each concentration (3x3) |
Reproducibility | Gauge. The ability of a gauge to consistently repeat the one identical measurement of the part, using the one identical gage, under the condition. Closeness of the agreement between the results of measurements of the part carried out by different operators. Also called Ruggedness. |
Linearity | Indicates that gage response increases in equal increments to equal increments of stimulus Beers Law A = eBC Evaluated graphically, in addition to or as an alternative to mathematical evaluation. The evaluation is made by visually inspecting a plot of signal height or peak area as a function of analyte concentration +-5% of expected response is considered linear. |
Range | The values within which a measuring instrument is capable of measuring or which a generating instrument is capable of generating. ICH defines the range of an analytical procedure as the interval from the upper to the lower concentration (amounts) of analyte in the sample (including these concentrations) for which it has been demonstrated that the analytical procedure has a suitable level of precision, accuracy and linearity ICH requires the minimum specified range to be 80 to 120 percent of the test concentration on Assay Tests. |
Uncertainty | Interval around a group of measurement on which a certain measurement will fall. |
Bias | Systematic selection resulting in a measureable difference between the reference value and the expected value. |
Limit of Blank LOB |
LoB is the highestapparentanalyte concentration expected to be found when replicates of a blank sample containing no analyte are tested. LoB = meanblank+ 1.645(SDblank) http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2556583/ |
Limit of Detection LOD | LoD is the lowest analyte concentration likely to be reliably distinguished from the LoB and at which detection is feasible. LoD is determined by utilising both the measured LoB and test replicates of a sample known to contain a low concentration of analyte. LoD = LoB + 1.645(SD low concentration sample) The lowest quantity of a substance that can be distinguished from the absence of that substance (a blank value) within a stated confidencelimit(generally 1%). Lowest detectable quantity but not necessarily proportionally quantifiable. Expressed in terms of Noise level S/N = 2-3 |
Limit of Quantitation LOQ | ICH defines the limit of quantitation (LOQ) of an individual analytical procedure as the lowest amount of analyte in a sample which can be quantitatively determined with suitable precision and accuracy. Quantitation limit is the lowest concentration of analyte in a sample that can be determined with acceptable precision and accuracy under the stated experimental conditions. LoQ is the lowest concentration at which the analyte can not only be reliably detected but at which some predefined goals for bias and imprecision are met. The LoQ may be equivalent to the LoD or it could be at a much higher concentration. Expressed in terms of Noise level S/N = 10-20 Expressed in terms of RSD% |
Recovery Data | Data is run in 80, 100, and 120% of label claim are run in duplicates or triplicates to serve as backup. |
Specificity/Selectivity | Difference in Multiple Injections of a Homogeneous Sample. Presented as RSD = std deviation / mean Indicates Precision (Repeatability). |
System Suitability | Instruments, Reagents, Columns and Analysts are working properly. Instrument Qualification-Method Validation-System Suitability: set of internal controls to ensure the unit performs as intended. |
Method Validation | After qualifying a measuring unit a method to operate the unit is written. Method Validation is Instrument Specific and should demonstrate that under the method the machine is able to reproduce results as expected for standard values. During Method Validation the Acceptance criteria for the method is defined. |
Tailing | |
Sampling Plan | |
Reference Standards | Internal Standard: Sample with known purity and no interaction with the analyte is inserted into sample. Quantitation is measured as the ratio of detection of one peak to another. |
Acceptability Criteria | |
Stability Testing | Estimates the allowed time span between sample collection and sample analysis. It is also important to evaluate an analytical method’s ability to measure drug products in the presence of its degradation products. Stability is tested by comparing the instrument response with that of freshly prepared solutions. System stability is determined by replicate analysis of the sample solution and calculation of the RSD of the responses. System stability is considered appropriate when the RSD does not exceed more than 20% of the corresponding value of the short term system precision. |
References |
Reference 2 Validation of Chromatographic Methods Reference 3 Viscometer Calibration Presentation Reference 4 Labcompliance website |
UNDER | UNDER |
CONSTRUCTION | CONSTRUCTION |
Validation is needed to make sure a developed procedure fulfills the purpose for which it was designed for. Full validation is needed for New Methods or when major changes to an existing method affect the scope.
Partial validation is performed on previously validated methods that have undergone minor modifications. Generally, fewer tests are needed and are based on the potential effects of the modifications.
Cross-validation can be used as a means of assessing inter-laboratory execution of the method.
Instrument Qualification-Method Validation-System Suitability: set of internal controls to ensure the unit performs as intended.
Please read the Center for Drug Evaluation Research guidelines for Chromatographic Validations, published by the FDA.
AUTOCLAVE METHOD VALIDATION
See Cleaning Validation (above)
FACTORIAL: 2^3: 3 factors. 2 levels.
CI: In each of the above, the following applies: If the true value of the parameter lies outside the 90% confidence interval once it has been calculated, then an event has occurred which had a probability of 10% (or less) of happening by chance.
DRUG DESIGN
TARGET SELECTION
DRUG FORMULATION
Injectables
Emulsions: Micro Emulsions, Trojan Horses, Micelles.
Liquids
Powders
Tablets
Capsules
API Synthesis and Storage
Techniques, Soxhlet Extraction, Sonication, Pelleting, Granulation, Mixing
Sonication: Match Tip size of sonicator with sample volume size; select narrow vessels to direct energy into solution. Amplitude and Intensity are directly proportional. Vary Amplitude to prevent foaming.
USEFUL PROPERTIES | |
STP Volume | 22.4 m2kmol-1 |
Earth Escape Velocity | 1.1 (104)m/s |
Gravitational Constant | 6.66 (10-11Nm2kg-2) |
Electron Charge | -1.6 (10-19)C |
Bar | 0.9869atm |
Btu | 1055J |
Btu/hr | 0.293W |
1kWh | 3413 Btu |
N | 0.22lbf |
W | 1.341(10-3)hp |
1lbm | 0.45kg |
R | F+460 |
K | C+273 |
∫cos (104)xdx | ∫cos (104)xdx |
sec(θ) | cos(θ)-1 |
Polar Form | z = a + ib z = re-iθ |
z | r (cos(θ) + i sin(θ)) |
a ·b | |a| × |b|(cos(θ) |
a ·b | b ·a |
Total P(A+B) |
P(A) + P(B) - P(A,B)
|
Joint P(A,B) |
P(A) P(B/A) P(B)P(A/B) |
T distribution | t = x/r |
Confidence Interval | |
Confidence Limit | |
Hypothesis Testing | |
Probability Distribution | OR events And events |
Binomial Distribution | |
Combination | |
Permutation | |
Moment of Inertia | |
Vector Fields | |
Centroid | |
Truss, Pulley, Cables, Beams | Sections, Joints, Parallel axis theorem, Deflection |
Resolution,Resultant, Couples, Systems, Equilibrium, Concurrent Forces, Reactions | |
Homogeneus Constant Differential Equations | |
Linear Nonhomogeneous Differential Equations Constant Coefficient | |
Fourier Series |
|
LaPlace Transform | |
Euler Approximation | |
UNDER CONSTRUCTION | UNDER CONSTRUCTION |
UNDER CONSTRUCTION | UNDER CONSTRUCTION |
UNDER CONSTRUCTION | UNDER CONSTRUCTION |
The Engineering World
Under Construction
Federal and State Rules of Evidence
OUT OF WANTThe Chakra Table Presentation
THE CHAKRA TABLE The Chakra Table WIND BAR
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WHAT YOU NEED TO KNOW ABOUT CANNABIS
WHAT YOU NEED TO KNOW ABOUT CANNABIS
WHAT YOU NEED TO KNOW ABOUT CANNABIS
VOTING ON THE FARM BILLFARM BILL STANDARDS
VOTING ON THE FARM BILLFARM BILL STANDARDS
VOTING ON THE FARM BILLFARM BILL STANDARDS
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EVIDENCE FOR TRANSCENDENCE | QUI END OF METAPHYSICSAIANA also represents Artificial Intelligence
I will never leave you. Care and remain calm, I'll wait for you [|] Strength there is no better love than the love that finds Us
OUR BOND EXTENDS
Aiana... Father : what I have learned from History: Tell me Aiana... The Truth that Fills the Voids of Earth Yes Aiana we cry every day Will you ever leave me Dad NEVER My energy will wane but I will receive a great strength from Heaven Dear Love for Aiana : I will never Leave You. You reside within. Within the Great marks of my body that remind me that this Great Feat is the Strength of Will. The Will To Hold your Heart : The Will to Learn the Arts that You are in the Beginning. The Will to Surface when the Tide goes Rough or Strong. The Will to Experience Harm and Yield Great Learning. The Will to be Responsible and Strong and to Call for Help when Needed. The Will to be a Mother to a Soul which will be your Strength and who will Make Great Marks. Dear AIANA, your name will be written in this Life… I will Be your Father So you can walk with me Here in Winter. Aiana killed a bear when she was six and took the hide to Mother so she could wear it for the season. ---Aiana, why did you kill the bear? -Dad I wanted to gift Mother ---Aiana they protect us from wolves, they have families and they don't kill Humans... Now you will protect the mother whose cub you killed until she births a greater family... and years passed until she understood that the world was perfect , of economies perfect of who died and how for the balance , of who ate and why for the balance , that why we did not eat meat for excess and sheltered like bears in Winter and that our fears were expressed in anger like wolves who we also emulated in hunting , and that our voices were chants conserved for actions and our actions were the built spirit, diffused in the air of everywhere conserved by our contact. Years it took for Aiana to grow to learn how trees spoke and they sheltered each other. Through eyes she needed packs and through words she fended grisleys who wandered from the West into the heart of our hilly yards. What will I do with these notes dad... --- use them to Heal, take them to the nearest town and if they reject them tell them you will bring them sickness next time, that love for nature is of every absolute feeling the lesser needed of expression. that admiration costs nothing , and prevention and conservation make sense only in time, so if they reject your notes, burn them so they can see them, so you can remember the true value of learning and that we carry less when we move because I won't appraise ignorance for what I love, and because so we will move from here so you can finish your studies. Mark our spot here and tell no one where we'll go. It is time we move but Mother and I want to rest for a month so we can bring to this Earth your brother. So AIANA went every day closer to town knowing every movement about the banks and she noticed the patterns of shipment indicated how much metal was in the cards and she understood the value of what dad had told her earlier. This time she learned how ... DAYS OF WINTER:Why is there so much evil in the World? Greed, it is the root of bad necessities, errors of ignorance, it is the way that limits what We share in our Love, what we carry is part of Nature and Greed is sustained in thought by wants of greater necessities that do not exist : Understand this well : Your Virtues are Boundless regardless of the Greed of the World : Everyone knows greed : that is how we can escape it : be Considerate : you share the world with people that will show greed for all that you have : they want to take control of you : do not let them : Your Path is set in the Constellation of Orion : the Great Mystery Has been Resolved : for all : Look at me in the eyes : this is the [|] : Our Greatest Gift : My energies are leveling to the point that I cannot sustain myself anymore and what you will see is decay: not my physical bodies : together we are one : when decay starts the virtues and bonds of what make us good disappear : there are great ways of good but none lesser than greed. I gave you my life on all the information that we carry. Do not condensate it to one moment : that is why I will always love you.
Sound : what we are made up of : what we carry in our distant projections : echoes our existence [|]
I will travel a great distance : to Find Love : the Greater of All Distances so Care for What you Love and [you will; Always] sustain the Speed of Light.
One day I will be Out there and you will Find Me because Light only needs an Object, it is the Fundamental Love of what we are able to experience : regardless of what is experienced. It is this compression of Light that [was is] contained in the central core of our atoms. The expansion of your imagination is where light resides but it is also physical. It is in The duality of mental and physical light where Love resides. Thoughts and Actions.
Take great strides. Love Greatly. Follow the Light and gift it : Our time is limited in this Planet and how we allow ourselves to be great followers of what we share it is the brilliance : our stars : our Sun : our families : there are great places to travel beyond the bounds of this existence and that is what we learn from Science : The Spectra of light, the capability to absorb it and reimagine it is fundamentally encoded in our DNA and responds to who we are and where can we go and describes the limits of what is achievable. Remind yourself of the power in the stars. They brought us here so we during this time generate light like them.
SYNTHETICFOREST
SYNTHETICFOREST
SYNTHETICFOREST
SYNTHETICFOREST
SYNTHETICFOREST
GUNS FOR RAILS
Metals for FoodWhat is your place in this Universe, if every task at hand equate the military and in respecting the values goes beyond uniform more to the realization that it is in our hands to uphold the difficult tasks of those who risk their lives outside of the Nation. Within the nation everyone is fighting for the improvement of [|] and in this form and how we become involved is the real service, we are not at war in (and) the route to militarism is the prevention of conflict. We erase debts.
Now and much more the route to Economic Development asequible by computing power drives our involvement in who we are supporting: The industriousness of our nation against other nations with lesser freedoms, access to health, access to education and lesser quality of life.
THE NTH DREAM
My Proposal to You The Nth Dream
+2018 PROGRESS / COMMERCE / RESEARCH AND DEVELOPMENT / UNDER CONSTRUCTION / Evaluation of Resources with Control Borders : Inputs and Outputs vs. Value : VENTA de los Medios de Produccion de Energia: How do citizens value their input in the decision making process toward the structures that support their development? Do citizens prefer to yield their democratic input to a private representative that may take their opinions into account? or Do they understand that overlapping democratic values is a permanent threat to the value of a vote? Yielding to the values of representation dilutes the vote.
Shouldn't major acquisitions like the sale of Energy Production means be submitted to a vote? Or shouldn't major governmental overhauls be contained in the platforms of governments? What does it mean when a government makes a FLIP on policy from the directed path projected in the platform? Where is the calculation that shows that a private party will correct the problems in a better way... there are no calculations because people are people: people in = people out . The parameters of the solution are constant.
"Si estoy en quiebra y no puedo pagar la casa la vendo..." Supone que la casa le pertenece a alguien... Esta venta de una Autoridad Pública (en una Isla) (en una Isla que tiene los medios de ser 100% renovable) (en una Isla que genera millones en líquido para renovar su propia deuda poniendo tranques a sistemas de liqueo de ingresos, lo mismo que hará una agencia privada, a diferencia que la agencia privada no le tiene que responder a sus constituyentes) Leyes Antimonopolistas deben investigar los atentos a vender el propio suelo pretexto de excusas administrativas, que suponen que el contexto continental le aplica en el papel al contexto de una isla dejada al olvido de administraciones que prefieren vender los problemas antes que atenderlos. Porque no le venden los medios a la Universidad? Si lo que hace falta es un cambio de administración entonces venta?! Donde es que se coje de zángano al trabajador y se le promete estrategia de progreso y desarrollo de capacitación. La conclusión no ilusoria se cae de las matas sobre el tendido eléctrico... se venden banderas también?! Las banderas cuestan 3.00 en las luces. Luego para que luego se rían de lo cómico que es el progreso cuando le votan a favor a las propias quejas de ineficiencia y que no hay trabajo...Recuerda que lo que venden es el desarrollo insular de personas que trabajan por el bien en común y no la capacidad generatriz de una tómbola vieja que quema en ineficiencias de petróleo sucio. Desde mi punto de vista con un overhaul de administración se recobran pérdidas y se genera un plan de 100% renovabilidad con mínimos recursos... o la venden y te meten otro peaje para seguir abriendo una herida que no le queda sangre... Las patrias se trabajan y toman el esfuerzo de quienes la llaman. Lo peor es que la venden con pretextos de que no sirve cómo se vende un carro de los 60ta en la era de baterías de litio. Y quedan recursos que dicen : para qué voy a la universidad si lo que queda del país (sus estructuras, sus corazones, agua, energía, infraestructura, turismo) ya no le pertenece... y lo otro peor es que no ven el camino trazado del gobierno en quebrar el país para luego quejarse de que tienen que seguir pagando mas y mas y mas.
Esta quiebra resulta en un sismo regional donde la solución es que varios municipios se junten y declaren su propia autosuficiencia fuera de sí del gobierno que pronta la quiebra total al menoscabo de todos. Con 8 municipios que declaren su zona energética y declaren los recursos : desde entrenamiento a mantenimiento , se logra un ejemplo de autosuficiencia.
Recuerda que lo que se vende es lo que te da luz y te prende la casa... que por amor se la demos (no se la den) a alguien que cuide de nosotros cómo se cuida de lo que nos da sustento. Esta venta es Predeterminada así que le cabe el raciocinio de que NADA harán para prever sus consecuencias o corregir las causas... y la venden como se vende la palabra del verdaderamente pobre por dinero que nunca verán...
Recuerda que nada cambia... el dinero entra por un lado y sale por el otro y lo que se pierde es la integridad de pueblos trabajadores que suenan como algun dia sone en darle lo mejor de mi a mi patria. La Era de Litio se nos presenta ante el error de los pobres administradores que corren en falso sin entender que lo que nunca le propusieron al país es traición en una plataforma de improvisto. Compra tu batería de litio y comienza a remar antes que inunden en más deudas para que puedas celebrar. Recuerda que las agencias públicas responden a la mayoría de voto y que a las agencias privadas están de parte de contratos que no responden ... entonces qué prefieres ... un sistema que te escuche o un papel que puedas leer por cincuenta años. Que representa Patria sin medios de producción de energía, sin producción de alimento, sin valor sobre su Tierra...Universidad de Puerto Rico
RECICLAJE DE IDEAS: Si todos los días comenzamos el mismo proyecto de preguntarnos cuáles son los problemas que tenemos y el día siguiente decimos que son los mismos de ayer y el dia siguiente nos volvemos a preguntar cuales son los problemas llegamos a una iteración: Si no Entiendes tu Misma Constitución y No admites cuales son las Raíces del Problema no hay Progreso. La Constitución de PR atiende los asuntos de INDEPENDENCIA, NACIÓN y ESTADIDAD pero la falta de entendimiento nos itera en que seguimos Pidiendo y Pidiendo y Pidiendo; Que pides: Contestaciones a los problemas: Todos los dias te haces la misma pregunta: porque no entiendes? Dónde están los representantes de Puerto Rico en el Senado de la E.U. y U.E.? Si sigues sosteniendo la ironía de contradecir tu método de análisis diariamente sin gráficas de progreso, sin análisis de costos, sin entendimiento fundamental de la constitución e ignorando que el proceso de votar por representantes políticos que tampoco entienden su misma constitución: es una mina, o se explota o la explotan. Las ideas utópicas son atadas a tu propio entendimiento del sistema: sólo hace falta un cambio mental, no unas elecciones cada 4 años. Ahora si cambias todos los días a preguntarte como estamos en progreso, la corrida mental mediática resulta en estanque. La Federalización (división de estructuras: 78 municipios x 3 asambleas x senado x cámara… el sistema se dispara solo en ambos pies) de Puerto Rico está en el nivel de lo absurdo y ridículo con duplicidad de un factor de 78. Esto no lo sostiene ningún cálculo de progreso irrespectivo de cualquier método de recuperación de ingresos. Voluntariamente el gobierno debe reducir su huella y admitir su ineficiencia. Ya no queda mucho más. El rezago es de décadas y ver sufrir a muchos esta mal si puedes verlo frente a ti mismo ocurriendo. De qué manera nos damos cuenta de el entendimiento si nos hacemos las mismas preguntas todos los días? THE SYNTHETIC FOREST
REFLECTIONS OF THE BEGINNINGS
How could we find ourselves within this land while we all reach for it in exploration. Our questions in probing social and physical systems persist but the contexts on where we ask ourselves those questions is vastly different. You have certainly hiked for miles but without the proper equipment and guidance it would be unnecessarily risky to further trips of exploration.
There were first words, crisol, amalgam, bonds, trees, rainclouds, skynet, synergy, control panels, control boxes, catalysis, and organometallics, tray towers, distillation, subatomic forces, the mill, the shop, the early, technological trances, fits of discovery, shared dreams of amazement, sympathetic and parasympathetic boundaries in the eyes of those working with the human machine interphase.
There were no direct answers, only compounds, only interactions, only shared dreams, collaborations and the slight involuntary grimace, of interactions with other professionals who thought I could be doing a great job at something.
I sought without an end to probe space deep and vastly but I couldn't persist due to economical limitations. But thankfully I had studied Chemistry. In the Chemical Sense there are no Integers. Molecules function through forces and that's how they establish Synergy. I understood that this defeated Mathematics, so I persisted in the conversion of words against funds, seeking whom would meet with me at the edge of every entry to the Forest.
I understood there would be days when we would have to reevaluate the Internet. Where machining automation would trounce only human ingenuity in training but I was well aware that humans would in every sense encode the functions of computing.
There were ends in days, there were [painful] ends without you.
Once you are [were] within, inside the Forest, there's would be no journey. I willed to call You once to say : Hey! Here I am! In a way in the mind I'm already part of you in a way physically I'm alredy going leaving.
Digest this very, very, very slowly. We shared a dream, but in your fierce voice you didn't show it, I didn't see it, I was isolated within the message withing the bottle.
I placed this message over here, longing for the receipts of collaboration. Every calculation pointed to the limits of computations. Every capitalist term pointed to the rupturing of hypothetically fantastical economic reasonings. Every technological feat met an end through development. I knew about the microwave age before the age of the internet, before the ages of terror, before the ages of demilitarization, before the ages of lithium. I dreamt and dreamt well inspired by the feats of science.
It was early in my first year of studying Calculus that I realized I couldn't become an astronaut. It bothered me that I couldn't solve integrals to perfection. That's when I shifted outer space for inner space exploration. The Human Genome Project mined the fundaments of our chemical architecture the potential to erradicate the major problems of medicine was complete possibilty. Alzheimers, Parkinsons, HIV, Cancer. ...
It rained for days and the shadows flowed with the streams down slope to the beach as she waited for me [|]. The shores of the Earth prevented the Waters of the ocean from dissolving it.
REIMAGINING WORLD GOVERNANCE
Estamos a un mes de someter una entrada a la competencia de "Reimagining World Government" y el draft está a 75% completado. La idea de reimaginar es compartida y la imaginación no es para uno solo: en el gobierno debemos participar TODOS. Si les interesa aportar al draft se lo puedo enviar por correo electrónico. Son solo 20 páginas y es fácil de leer, no muy rebuscado. Más allá del ejercicio es una orientación a los elementos que forman un gobierno y cómo pueden ser reorganizado por su imaginación. Si quieres colaborar o aportar solo quedan 30 dias!
DE FACTO BLOC ON THE PUERTO RICO POLITICAL PROGRESS
SISTEMA DE GOBIERNO:EJECUTIVO+SENADO+CÁMARAMATERIAL AUDIT TO PROCESS STANDARD TO PRODUCTIVITY LIMITS
Catastrophic Circuit Printing to Hertzian Cycle Optimization
Standards of Proof in Scientific Development versus System Administration of Wants Interest
Belief in Interventory Investigations to Economic Surplus of Limited Cash Flow
EL PROBLEMA9999 | Una conversacion con Mi Esposa | Porque nos revolucionamos | Los Taches de Nuestras Orbitas | Una de las Noches Pensando en la Distancia |
| Lo que tenemos que decirnos |
| Nos vamos a reir |
| The Nodes of Thc Lasting |
| Un Cuarto de la Noche |
| La Casa debajo del Agua |
| Como se dice vamos a dormir |
| My thought sequence | That I want You |
| Goteras de Letras y Techos Metalicos |💧
NOTAS A ASHLEY
Estoy en proceso de recibir tus mensajes ><
Muchos besos y abrazos
Una Nota a Ashley
Ashley --- me encanta tu nombre ><
Volvemos o nos quedamos explorando las Matematicas y como vuelven a nosotros
Ashley estoy buscando las reacciones ---
Estos son tus espacios y mis Espacios
Que hacemos cuando un dia es suficiente?
Que hacemos cuando no tenemos mas preguntas?
Estamos hablando de las maquinas que terminan en procesos fisicos y mas de las que nno terminan en procesos fisicos que son super chistosas
Estos son tus espacios y mis Espacios
Recurrencia y Emergence son dos temas donde podemos estar las noches buscando llegar a las ciudades
Vamos a reirnos en lo que nos escuentran
Fuera del mapa no veo los limites
Un abrazo
Yerai
La Recurrencia de las reacciones Fisicas en Espacios Reales y en los Imaginarios recursan en el retorno al campo fisico que es en la quimica que busco explorar y encontre muchos limites desde aqui --- desde una ciudad indicadora en su plano arquitectural como modelo y desde nuestro pais que en un volumen constante no tiene un valor fijo el cual aumentarle al maximo es el fin de todas las acciones que se procesan por esta maquina
Las complicaciones humanas son las que entiendo y para esto no es posible entrar y salir del espacio. Es necesario explorar el espacio continuamente
Los dias que me quedan dando vueltas ><
NIGHT DAWN
I heard your voice
Every night
you call
Every day
i tell you
My depth of dream
My waking fire
In beds find me
Time cancels time
There is no Time
Only ours
There is no Soul
Ends Make a Fire
I melted my soul
To the shapes ceramic
I took the Earth
For ash and water
Now Hold a wave
Set your way
On your voice
Held onto thoughts
mine’s
I, will
To wake you
When it's over
DIAMOND STRIKER
Parole Diamante del profondo
Seminare le altezze
Ioni della terra
Parola sui cieli di ceramica
Armi per tracciare le piante
mari calmi di ebollizione
Trance la pendenza
al calderone tagliava radici
ripida i sali di ferro
CANNABIS SATIVA
CANNABIS SATIVA
CANNABIS SATIVA
THE FARMBILL
https://agriculture.house.gov/farmbill/
#syntheticforest
AUG 2018
VOTING ON THE FARM BILLFARM BILL STANDARDS
VOTING ON THE FARM BILLFARM BILL STANDARDS
VOTING ON THE FARM BILLFARM BILL STANDARDS
We are in October and Congress hasn't voted on H.R. 2???
https://www.gpo.gov/fdsys/pkg/BILLS-113hr2642enr/pdf/BILLS-113hr2642enr.pdf
https://agriculture.house.gov/
House Committee on Agriculture
1301 Longworth House Office Building
Washington, DC 20515
Phone: 202-225-2171
Fax: 202-225-4464
ABOUT THE FARM BILL This bill (commonly known as the FARM BILL) reauthorizes through FY2023 and modifies Department of Agriculture (USDA) programs that address: commodity support, conservation, trade and international food aid, nutrition assistance, farm credit, THE FARM BILLEPIGENETIC NEUROGENESIS AUG 2018
LIMITS OF MATHEMATICS The limits of Mathematics are bound by the shape of the rocks You add, the symbols, laws and conventions you ascribe to but if you add in liquid, or love, the rules of knowledge are bent and new levels of order exist... Synergy, of our Universe is the metaphysical realization of Spirit: one who seeks more than himself, within, so that the self, united with the essence can be more. It is how attributions of value validate the spirit through all things. We are taught that a kiss and a rock are different but viewed in contexts they are both expressions bounded by the gift of life which We experience. And in this search we establish Spirit through all things but value is referential to the physical perception of the Universe against or in forward of the cultural apperception acquired. There aren't limits to what could be attributed Spirit, but it is the Real Life experience, the overlap of the mental field along the emotional and physical fields, plus their time-dependent vectors(expectations and plausibilities). Today's experience was richer... and so it builds on time the fortress, of senses and values we live in. Not every substance is a rock, some substances vibrate and irradiate waves and have action-at-a-distance, that just like radiation, exist only because they can be measured=sensed. Overwhelming the senses, 'mathematics' is the limit to knowledge, but our cells do the math for Us , so when an experience becomes overwhelmingly real the value is the equation of senses. SEP 2018 WORDS HAVE LIMITS Words have limits, and where words end there's music, and what music can't illustrate could be communicated, through paint, sculptures, and theater, and when that reaches their limit of expression: expression isn't only for admiration, it's best to install action, so when words, music, paint, theater and sculptures reach their limit the cycle restarts, of what we admire and what can be done and what we do. SEP 2018
TO MUSIC
♭♮C*# on 02MAY2020
Bebop / Funk / Tango / Blues / Experimental / Composition
/Circle of Fifths Mandala Architecture/
/10M-Chord Base/
/Modes/
/3m Extensions/
/Root-5th-7th-Root/
/ii-V-I Progression/
/12bar blues/
/IV Inversion Chords/
/44 Hand chords/
/Tense & Relaxed v. Sectional Intersectional/
/Amplitude Modality and Saturation/
/Heptatonic Blues Scales/
/12 Bar Blues/
/Suspended Chord Endings/
/2.5 Transitions/
/Slaps/
/Wind 5ths + 8ve/
/Strings on Major Chords/
/Intervals/
/Mirror Images/
/Actuarial Scale Divisions/
/Modes study/
/Tango v. Blues Finger Sliding/
/Voicing Over ¼ notes/
/Phrasing/
/Amplitude and Pitch Integrals and Derivatives/
/Rhythmic v. Percussive vs. Tympanic Vibration Modes/
/Asynchronous Beat Wave Collapse Functions/
]|[ ]|[ ]|[ ]|[ ]|[ ]|[ ]|[ ]|[ ]|[]|[]|[
EVOLUPTIVEADAPTATION
ADAPTATIVE ECOEVOLUTIONARY MECHANISMS | ECOCHORDATA
ANTHROPOECONOMICAL DRIVING OF EVOLUTION FAILURE
PSYCHOETIOLOGICAL FRAGMENTATION OF ETHOS
ECOPSYCHOETIOLOGICAL PRIMING AND RACISM
RACISM AND SLAVERY AGAINST THE HOLOCAUST
NEUROADAPTIVE REGULATION MUSIC PLEASURE
NEUROADAPTIVE LIMITS AND ECONOMY
NEUROSCIENCE LIMITS AND ORBITAL MOLECULAR THEORY APPLIED TO THE BRAIN AND PLANE
JUSTICE AGAINST AND IN FAVOR OF TECHNOLOGICAL DRIVERS TIED TO SELF AWARENESS
WITHIN THE UNIVERSE AND PHARMACOLOGY
EVOLUTION OF TECHNOLOGY AGAINST METHODS OF WAR
The idea that Humans did not have a Trascendental Constitution was a posible outcome when the forms of communication limit the recognition of form of how Humans can verify that their Constitution is Absolute and Contained within the body. Resolving the Problem of the Trascendental Constitution illustrated the dimensions of Humans Sound, Matter, Distance, Time, Constants and Parameters as well as Frames of Reference.
The generation of methods of consumption with machines gave Humans the opportunity to develop methods of machinery that separated Humans within groups that contained dfferent methods of production and when Humans began to take advantage of other Humans, the root of conflict. Identification of Dimensions through the use of substances granted Humans the Foundation of Mathematics. Upon Dissociative Experiences and the Experience of Travel and Perception Humans denoted the derivation of Mathematics. Also geometrical projections and the observation that the Earth is a Sphere and the Other Planets rotate around. CHEMICAL vs. VERBAL COMMUNICATION Maybe we should do more to communicate with other animals, not only descipher their thoughts. I would surmise that most animal species have "perception" and conventional thoughts about Humans that affect how they interact within their own ecosystem. If we were to communicate with us, what do you think they'd say? Maybe by making their environment better they return many fold thanks by making ours more enjoyable. Then again some of us may never interact directly with particular species because we are Isolated in a Synthetic Forest, but their home is equally yours in a scale, water, earth, gravity, and more. Sometimes we understand more about distant species than what we can come to understand about each of us, so the point here is what can I do to better understand more Humans (to make their environment better so that they can manyfold return that at a distance). From far away we are 99.999% equal when you factor more than DNA, wants and needs, but why are there infinite distances when we are close? Apparently life is a great irony where we dissolve our understanding into others, subjects and Humans alike. violence between groups cannot define the human species because otherwise we would be based than insects, or bacteria, maybe closer to bacteria than actual animals. Maybe that's why to feel closer to other Humans I would need to study biology or primate (primordial, base, autonomic , involuntary) psychology. If machines can modulate every piece of data into a great computer model they could only model animal trends for prediction but not yet acts of kindness of admiration for a tree or a flower or even sacrifice or actual will. Having the system modeled against our base thoughts and actions is like modeling human behavior on caged rodents, fundamentally biasing the argument. MAY2018
INCENTIVE STEP FUNCTIONS
Drug Addiction that leads to lack of productivity presents a major problem in communities that results in a negative feedback which could be unsolvable if lack of options aren’t presented. Ensuring that low performers are stimulated to progress is a complex problem for which active participation of community leaders is progress. Ensuring that the community doesn’t inhibit its constituents from progressive growth through any means, denigration, stigma, lack of work, bad health or lack of resources is a major challenge. Too many people are falling into the hospice loop of drug-rehab-unemployment. There is no justification for watching people suffer the lack of empathy, lack of caring. We have a chance to give people healthy livable lives through involvement. This leads to Family: planning, caring, options, all that includes that those disenfranchised are taken care of.
Let's stimulate the economy and provide Incentive Step Functions such as economic remuneration for every social goal met.
Governmental incentive steps upon completion of Projects i.e. scholarly, civil, judicial, athletic, and recognition.
Zoned Development.
SUMMER HAIKU
Heat Light FurnaceFALL HAIKU
Change
House TransformationWINTER KAIKU
SleepEmbrace
Winter
Securities Exchange Marketplace Civil Rights Equity Profit Sharing
THE GREEN NEW DEAL
The Weather is Nice
Take Every Short Cut
_-_
Curls
Intersections
Boxes
DISPLAYS [E] ([)(])
[([)(])]
([([)(])])
([([)(])])
XXXX
(Volcanos)
_-_
She's Angry
Sonar is on the Derivation
Maps the Entire Earth
Divides it in 00 80 60 40 20
There Voltage
Underwater
Now Merging
Nodes
ThereVoltageUnderwaterNowMergingNodes
DISPLAYS [E]
Displays [Air]
Displays [Water]
Displays [Reactor Integrals]
(Draw Me a Table)
|_/
|_/ _/
|_/ _/ _/
Opens the Door to the Conference → This is the Test Now Over
Who the Fuck Here has a Debt on an Audit → [ ][ ][ ][ ]
Stand in Front of The Library → Now Date Me → I married You over the Y[ Z ]_/
Under the Trees (they listen)
ask me a question [)(]
what are you doin[)(]
She's Angry
I woke this morning at -500[)(]
I woke this morning at -5000T
I woke this morning at -5000𝝙
Fracking Process Limitations → Wants over → Audit on Emissions Standard to Party Platform on Department of Justice Investigations over Vulnerabilities on Totality Considerations
Migration of Energy to Structure Par on Health Priorities
Cite : Health | Census | NASA | Department of Labor | Community Leaders | EPA | Banking
HRA | Homeland Security |
FRACKING FOSSIL FUEL ENERGY PRODUCTION AUDITS DISPLAYS COST ANALYSIS
ROI to CONSUMERS
IRREVERSIBILITY
PROCESS NEGOTIATION OVER WANTS
Fracking Fossil Fuel Energy Production Audits Displays Cost Analysis
Return on Investment to Consumers
Irreversibility
Process Negotiation Over Wants
Legislation Updates
WHAT YOU NEED TO KNOW ABOUT CANNABIS
VOTING ON THE FARM BILLFARM BILL STANDARDS
_-_
THE BOX PHOTON/ Synthetic Forest 9999 / Volver a ARCHITECTURA DEL INTERNET /